syn-(E)-bis(fenchylidene) | 56956-28-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: syn-(E)-bis(fenchylidene)
• 英文别名: syn-bifenchylidene；1,1',3,3,3',3'-Hexamethyl-2,2'-bisnorbornyliden；(-)-Fenchylidenfenchan；Fenchylidenfenchon；(1R,2E,4S)-1,3,3-trimethyl-2-[(1R,4S)-1,3,3-trimethyl-2-bicyclo[2.2.1]heptanylidene]bicyclo[2.2.1]heptane
• CAS: 56956-28-6
• 化学式: C₂₀H₃₂
• 分子量: 272.474
• InChiKey: YWDNLLRZWAMTOR-IAXNQTQISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  syn-(E)-bis(fenchylidene) 生成 anti-(Z)-bis(fenchylidene)
  参考文献：
  名称：

  Chemistry and Structure of anti-(Z)- and syn-(E)-Bis(fenchylidene)

  摘要：

  anti-(Z)-Bis(fenchylidene) (3) has been prepared. The crystal structure of 3 displays an alkene torsion angle of 17.0-degrees and deformations of the carbon-carbon bond lengths and angles around the alkene center. The chemical behavior of syn-(E)-bis(fenchylidene) (2) and 3 was found to be affected by the steric strain.

  DOI：

  10.1021/jo00085a027
• 作为产物：
  描述：

  [(4R)-2,2,4-trimethyl-3-bicyclo[2.2.1]heptanylidene]hydrazine 在 selenium 作用下， 生成 syn-(E)-bis(fenchylidene)
  参考文献：
  名称：

  Back,T.G. et al., Journal of the Chemical Society. Perkin transactions I, 1976, p. 2079 - 2089

  摘要：

  DOI：

文献信息

• “Tied-back” carbocyclic intermediates in the preparation of very sterically strained olefins: Derivatives of tetra--butylethylene
  作者：Edward R. Cullen、Frank S. Guziec、Mitchell I. Hollander、Christopher J. Murphy

  DOI：10.1016/s0040-4039(01)82982-8

  日期：1981.1

  The preparations of the extremely sterically hindered olefins (12) and-(13) are described, and attempts to convert these compounds to other derivatives of tetra--butylethylene (1) are outlined.

  描述了极受空间阻碍的烯烃（12）和-（13）的制备，并概述了将这些化合物转化为四-丁基乙烯（1）的其他衍生物的尝试。
• Synthesis and properties of monomeric selenoketones
  作者：Thomas G. Back、Derek H. R. Barton、Michael R. Britten-Kelly、Frank S. Guziec

  DOI：10.1039/c39750000539

  日期：——

  The preparation and reactions of di-t-butyl selenoketone (Ib) and of (–)-selenofenchone (IIb) are described; fenchylidenefenchane (VI) has been synthesised.

  描述了二叔丁基硒酮（Ib）和（-）-硒烯酮（IIb）的制备和反应；fenchylidenefenfenchane（VI）已合成。
• Chemistry and Structure of anti-(Z)- and syn-(E)-Bis(fenchylidene)
  作者：Peter R. Brooks、Roger Bishop、James A. Counter、Edward R. T. Tiekink

  DOI：10.1021/jo00085a027

  日期：1994.3

  anti-(Z)-Bis(fenchylidene) (3) has been prepared. The crystal structure of 3 displays an alkene torsion angle of 17.0-degrees and deformations of the carbon-carbon bond lengths and angles around the alkene center. The chemical behavior of syn-(E)-bis(fenchylidene) (2) and 3 was found to be affected by the steric strain.
• Back,T.G. et al., Journal of the Chemical Society. Perkin transactions I, 1976, p. 2079 - 2089
  作者：Back,T.G. et al.

  DOI：——

  日期：——