The constituents of Schizandra chinensis Baill. IV. The structures of two new lignans, pre-gomisin and gomisin J.
作者:YUKINOBU IKEYA、HEIHACHIRO TAGUCHI、ITIRO YOSIOKA、HIROSHI KOBAYASHI
DOI:10.1248/cpb.27.1583
日期:——
Two new lignans named pre-gomisin (1) and gomisin J (2) were isolated from the fruits of Schizandra chinensis BAILL. (Schizandraceae). The structure of the former was elucidated as (2S, 3R)-1, 4-bis (3´-hydroxy-4´, 5´-dimethoxyphenyl)-2, 3-dimethylbutane (1) by its preparation from guaiaretic acid. The structure and conformation of the latter were elucidated by chemical and spectral studies.
从五味子果实中分离得到两种新的木脂素,命名为 pre-gomisin (1) 和 gomisin J (2)。 (五味子科)。由愈创木酸制备前者的结构被阐明为(2S,3R)-1, 4-双(3´-羟基-4´,5´-二甲氧基苯基)-2,3-二甲基丁烷(1)。后者的结构和构象通过化学和光谱研究得到阐明。