| 1160424-50-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1160424-50-9
• 化学式: C₅₃H₈₇NO₅Si
• 分子量: 846.363
• InChiKey: VXGXVHFRMCRJIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.99
• 重原子数：
  60.0
• 可旋转键数：
  26.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  57.23
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  在 盐酸 作用下， 以 水 、 丙酮 为溶剂， 反应 3.0h， 以75%的产率得到
  参考文献：
  名称：

  Thermally Stable Nonlinear Optical Polymers Based on Polyimides Substituted with Chromophores Containing Julolidine Moiety

  摘要：

  We designed and synthesized a NLO chromophore adopting the concept of shape modification as well as possessing high thermal stability. The chromophore was featured by a phenylene ring as a conjugation bridge, a bulky alkyl chain attached on the side of the conjugation bridge, and julolidine moiety as an electron donor. The NLO chromophore was attached to the polyimide as a side chain, resulting in thermally durable NLO polymers. On set decomposition temperature of the NLO chromophore was measured 330 degrees C in TGA analysis. The NLO polymer exhibited high glass transition temperature of 150 degrees C and was thermally stable up to 250 degrees C. The polymer was quite soluble in common solvents and produced an optical quality film by spin-coating. The electro-optic coefficient of the film was measured using 1.55 mu m laser source, giving as high as 30 pm/V at the poling condition of 150 degrees C and 1 MV/cm.

  DOI：

  10.1080/15421400802329590
• 作为产物：
  描述：

  9-(4-bromo-2,5-bis((2-ethylhexyl)oxy)styryl)-8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline 、 N,N-二甲基甲酰胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 3.0h， 以45%的产率得到
  参考文献：
  名称：

  Thermally Stable Nonlinear Optical Polymers Based on Polyimides Substituted with Chromophores Containing Julolidine Moiety

  摘要：

  We designed and synthesized a NLO chromophore adopting the concept of shape modification as well as possessing high thermal stability. The chromophore was featured by a phenylene ring as a conjugation bridge, a bulky alkyl chain attached on the side of the conjugation bridge, and julolidine moiety as an electron donor. The NLO chromophore was attached to the polyimide as a side chain, resulting in thermally durable NLO polymers. On set decomposition temperature of the NLO chromophore was measured 330 degrees C in TGA analysis. The NLO polymer exhibited high glass transition temperature of 150 degrees C and was thermally stable up to 250 degrees C. The polymer was quite soluble in common solvents and produced an optical quality film by spin-coating. The electro-optic coefficient of the film was measured using 1.55 mu m laser source, giving as high as 30 pm/V at the poling condition of 150 degrees C and 1 MV/cm.

  DOI：

  10.1080/15421400802329590