(Z)-1,1-diethoxynon-2-ene | 91043-38-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Z)-1,1-diethoxynon-2-ene
• CAS: 91043-38-8
• 化学式: C₁₃H₂₆O₂
• 分子量: 214.348
• InChiKey: MUWPHRMERVXBEL-QXMHVHEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.91
• 重原子数：
  15.0
• 可旋转键数：
  10.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (Z)-1,1-diethoxynon-2-ene 在 甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.17h， 以23%的产率得到(Z)-壬-2-烯醛
  参考文献：
  名称：

  Synthesis and reactivity of Z and E functionalized allylic fluorides

  摘要：

  The allylic fluorides 1 and 2 are used as models to study the effect of the allylic C-F bond on the diastereoselectivity of reactions occurring on the vicinal double bond, as well as the compatibility of this C-F bond with various reagents. The configurational stability of the Z double bonds in enals and enones 1 and 3 is noteworthy. This allowed us to perform various types of reactions (including thermal Diels-Alder cycloadditions) on derivatives 1 with full control of the Z geometry. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2003.08.068
• 作为产物：
  描述：

  non-2-ynal 在 Lindlar's catalyst 吡啶 、 氢气 、 对甲苯磺酸 作用下， 以 乙醇 、 正戊烷 为溶剂， 反应 44.0h， 生成 (Z)-1,1-diethoxynon-2-ene
  参考文献：
  名称：

  Synthesis and reactivity of Z and E functionalized allylic fluorides

  摘要：

  The allylic fluorides 1 and 2 are used as models to study the effect of the allylic C-F bond on the diastereoselectivity of reactions occurring on the vicinal double bond, as well as the compatibility of this C-F bond with various reagents. The configurational stability of the Z double bonds in enals and enones 1 and 3 is noteworthy. This allowed us to perform various types of reactions (including thermal Diels-Alder cycloadditions) on derivatives 1 with full control of the Z geometry. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2003.08.068

文献信息

• Reactivity of α,β-unsaturated acetals and ketals toward organolithium reagents in pentane
  作者：Charles Mioskowski、S. Manna、J.R. Falck

  DOI：10.1016/s0040-4039(00)99926-x

  日期：1984.1
• MIOSKOWSKI, CH.;MANNA, S.;FALCK, J. R., TETRAHEDRON LETT., 1984, 25, N 5, 519-522
  作者：MIOSKOWSKI, CH.、MANNA, S.、FALCK, J. R.

  DOI：——

  日期：——