3-甲基-5-(丙-1-烯-2-基)环己-2-烯醇 | 1123219-06-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 3-甲基-5-(丙-1-烯-2-基)环己-2-烯醇
• 英文名称: 3-methyl-5-(prop-1-en-2-yl)cyclohexa-2-enol
• 英文别名: 3-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-ol
• CAS: 1123219-06-6
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: KGBYJUNQUOTCBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-甲基-5-(丙-1-烯-2-基)环己-2-烯醇 在 potassium peroxymonosulfate 、 2-碘苯磺酸钠 、 sodium sulfate 作用下， 以 乙酸乙酯 为溶剂， 反应 8.0h， 以91%的产率得到3-Methyl-5-isopropenyl-2-cyclohexen-1-on
  参考文献：
  名称：

  METHOD FOR PRODUCING CARBONYL COMPOUND AND PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND

  摘要：

  公开号：

  EP2085373B8

文献信息

• PROCESS FOR PREPARATION OF CARBONYL COMPOUND AND PRO-OXIDANT FOR PREPARATION OF CARBONYL COMPOUND
  申请人：Ishihara Kazuaki

  公开号：US20100041917A1

  公开（公告）日：2010-02-18

  The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R 1 and R 2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R 1 and R 2 combine the two carbon atoms to which they are boned to form an aromatic ring.

  本发明提供了一种通过氧化醇类化合物高效制备羰基化合物的方法。本发明的制备羰基化合物的方法包括在化合物(I)的衍生物或盐及氧化剂的存在下氧化醇类化合物的步骤，其中R1和R2分别独立地表示氢、卤素、硝基或酸性基团或烷基或烷氧基，每个基团可选地具有取代基，或者R1和R2结合形成它们所结合的两个碳原子形成芳环。
• Process for preparation of carbonyl compound and pro-oxidant for preparation of carbonyl compound
  申请人：Ishihara Kazuaki

  公开号：US08394995B2

  公开（公告）日：2013-03-12

  The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R1 and R2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R1 and R2 combine the two carbon atoms to which they are boned to form an aromatic ring.

  本发明提供了一种通过氧化醇制备高效的羰基化合物的方法。本发明的羰基化合物制备方法包括在化合物(I)的存在下或其衍生物或盐的存在下，在氧化剂的存在下，将醇氧化的步骤，其中R1和R2分别表示氢、卤素、硝基或酸性基团，或烷基或烷氧基，每个基团都可以有取代基，或者R1和R2结合成它们所结合的两个碳原子形成一个芳环。
• METHOD FOR PRODUCING CARBONYL COMPOUND AN PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND
  申请人：National University Corporation Nagoya University

  公开号：EP2085373A1

  公开（公告）日：2009-08-05

  The invention provides a process for the preparation of a carbonyl compound in high efficiency by oxidizing an alcohol. The process for the preparation of a carbonyl compound of the present invention includes a step of oxidizing an alcohol in the presence of a compound of the formula (I) or a derivative or a salt thereof, and an oxidant, wherein R1 and R2 independently represent hydrogen, a halogen, a nitro or acidic group, or an alkyl or alkoxy group, each of which optionally has a substituent, or R1 and R2 combine the two carbon atoms to which they are boned to form an aromatic ring.

  本发明提供了一种通过氧化醇高效制备羰基化合物的工艺。本发明制备羰基化合物的工艺包括在式（I）化合物或其衍生物或盐以及氧化剂存在下氧化醇的步骤、 其中 R1 和 R2 独立地代表氢、卤素、硝基或酸性基团，或烷基或烷氧基，每个基团可选地具有一个取代基，或 R1 和 R2 将它们所骨架的两个碳原子结合成一个芳香环。
• US8394995B2
  申请人：——

  公开号：US8394995B2

  公开（公告）日：2013-03-12
• METHOD FOR PRODUCING CARBONYL COMPOUND AND PRO-OXIDANT USED FOR PRODUCTION OF CARBONYL COMPOUND
  申请人：National University Corporation Nagoya University

  公开号：EP2085373B8

  公开（公告）日：2013-06-26