(1R,2R,3S)-1-acetoxymethyl-2,3,4,4-tetramethylcyclopentane | 1018966-53-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1R,2R,3S)-1-acetoxymethyl-2,3,4,4-tetramethylcyclopentane
• 英文别名: acetic acid (1R,2R,3S)-2,3,4,4-tetramethyl-cyclpentylmethyl ester；[(1R,2R,3S)-2,3,4,4-tetramethylcyclopentyl]methyl acetate
• CAS: 1018966-53-4
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: XETZXVIUAWDKIL-YWVKMMECSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (1R,2R,3S)-1-hydroxymethyl-2,3,4,4-tetramethylcyclopentane 、 乙酸酐 在 三乙胺 作用下， 以 乙醚 为溶剂， 生成 (1R,2R,3S)-1-acetoxymethyl-2,3,4,4-tetramethylcyclopentane
  参考文献：
  名称：

  通过振动圆二色性分析确定暗粉虱的性信息素的绝对构型。

  摘要：

  比较对映的纯净粉虱性信息素的对映纯样品的理论和实验振动圆二色性（VCD）光谱，可以确定昆虫信息素的绝对构型。

  DOI：

  10.1039/b717440c

文献信息

• ENANTIOSELECTIVE PROCESS FOR THE PREPARATION OF ENANTIOMERS OF SEX PHEROMONES
  申请人：COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH

  公开号：US20150361025A1

  公开（公告）日：2015-12-17

  The invention disclosed herein relates to an enantioselective process for preparation of biologically active (R) and (S) enantiomers of sex pheromones of the long-tailed Mealybug with high enantiopurity having significant biological activity. Further, the invention provides absolute configuration of synthesized R and S enantiomers.(I)

  本发明涉及一种手性选择性制备长尾粉介壳虫生物活性(R)和(S)对映体性别信息素的过程，具有高对映纯度和显著的生物活性。此外，本发明提供了合成的R和S对映体的绝对构型。(I)
• METHOD FOR EFFECTIVELY CONTROLLING COCCOIDEA INSECT PESTS
  申请人：Ecologia Y Proteccion Agricola, S.L.

  公开号：EP3732964A1

  公开（公告）日：2020-11-04

  The present invention relates to a method for determining the effective flow rate of at least one semiochemical for controlling at least one coccoid insect pest using an artificial semiochemical matrix, and use of the effective flow rate for effectively controlling at least one coccoid insect pest through the diffusion of at least one semiochemical.

  本发明涉及一种利用人工半化学物质基质确定至少一种半化学物质的有效流速以控制至少一种茧翅目害虫的方法，以及利用该有效流速通过至少一种半化学物质的扩散有效控制至少一种茧翅目害虫的方法。
• Enantiospecific synthesis of sex pheromone of the obscure mealybug from pantolactone via tandem conjugate addition/cyclization
  作者：Atul K. Hajare、Laxmikant S. Datrange、Samir Vyas、Debnath Bhuniya、D. Srinivasa Reddy

  DOI：10.1016/j.tetlet.2010.07.166

  日期：2010.10

  An efficient synthesis of an enantiomer of insect's natural pheromone is reported starting from chiral pool D-(-)-pantolactone. Highly stereoselective tandem conjugate addition/cyclization sequence and hydrogenation of exocyclic double bond are the key steps in the present synthesis. (C) 2010 Elsevier Ltd. All rights reserved.
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• METHOD FOR EFFECTIVELY CONTROLLING COCCOID INSECT PESTS
  申请人：Ecología y Protección Agrícola, S.L.

  公开号：US20210059246A1

  公开（公告）日：2021-03-04

  The present invention relates to a method for determining the effective flow rate of at least one semiochemical for controlling at least one coccoid insect pest using an artificial semiochemical matrix, and use of the effective flow rate for effectively controlling at least one coccoid insect pest through the diffusion of at least one semiochemical.