3,6,6-trimethylbicyclo[3.1.1]heptan-2-ol | 72257-14-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3,6,6-trimethylbicyclo[3.1.1]heptan-2-ol
• CAS: 72257-14-8
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: DODVNKCHFWJRHU-JQCXWYLXSA-N

反应信息

• 作为产物：
  描述：

  potassium (3,6,6-trimethylbicyclo[3.1.1]heptan-2-yl)trifluoroborate 在 Oxone 、 水 作用下， 以 丙酮 为溶剂， 反应 0.03h， 以98%的产率得到3,6,6-trimethylbicyclo[3.1.1]heptan-2-ol
  参考文献：
  名称：

  Oxidation of Organotrifluoroborates via Oxone

  摘要：

  A method for the oxidation of organotrifluoroborates using Oxone was developed. A variety of aryl-, heteroaryl-, alkenyl-, and alkyltrifluoroborates were converted into the corresponding oxidized products in excellent yields. This method proved to be tolerant of a broad range of functional groups, and in secondary alkyl substrates it was demonstrated to be completely stereospecific.

  DOI：

  10.1021/jo102208d