bis(3,6-di-tert-butyl-catecholate)bis(tetrahydrofurane)germanium(IV) | 1148042-03-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: bis(3,6-di-tert-butyl-catecholate)bis(tetrahydrofurane)germanium(IV)
• CAS: 1148042-03-8
• 化学式: C₃₆H₅₆GeO₆
• 分子量: 657.427
• InChiKey: CTKVBOMJWNWHPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 germanium(II) chloride dioxane 、 3,6-二叔丁基环己-3,5-二烯-1,2-二酮 以 四氢呋喃 为溶剂， 以79.2%的产率得到bis(3,6-di-tert-butyl-catecholate)bis(tetrahydrofurane)germanium(IV)
  参考文献：
  名称：

  Novel germanium(IV) catecholate complexes

  摘要：

  The interaction of germanium(II) chloride dioxanate with 3,6-di-tert-butyl-o-benzoquinone or with its mono- and dianion derivatives is attended by the redox transformations. The novel germanium bis-catecholate complexes were synthesized that contained coordinated ether molecules (THF (I), Et2O (II)) irrespective of the initial redox form of o-quinone. The germanium complex was also synthesized by the exchange reaction between GeCl4 and sodium catecholate. Complexes (I), (II) were characterized by NMR and IR spectroscopies, elemental and X-ray diffraction analyses.

  DOI：

  10.1134/s1070328408040027

文献信息

• Heterometallic Germanium(IV) Complexes Based on the N-Phenyl-Substituted o-Amidophenolate Ligand
  作者：A. V. Piskunov、K. V. Arsenyeva、A. V. Klimashevskaya、A. V. Cherkasov

  DOI：10.1134/s1070328422050074

  日期：2022.5

  low-valence center to the tetravalent state and is accompanied by symmetrization with the formation of the corresponding bis-o-amidophenolate and bis(catecholate) derivatives of germanium(IV). Digermylene oxide Ia synthesized by the hydrolysis of starting germylene I acts as the oxidant in the reaction with the nickel cyclopentadienylcarbonyl dimer and forms an eight-membered metallocycle supporting four Ge(II)–Ni(II)

  摘要 新型双金属配合物Ph APGe[M(CO) n Cp] 2 ( Ph AP 是 3,5- di- tert - butyl- N -(phenyl)- o -ami-nophenolate dianion; M = Fe, n = 2 ( II ); M = W, n = 3 ( III ) ) 是通过在二聚体 [Fe(CO) 2 Cp ] 2和[W (CO) 3 Cp] 2。化合物II和III的氧化用三氟甲磺酸银 (I) 得到顺磁性锗 (IV)邻亚氨基半喹啉，通过 EPR 光谱法检测。3,6-二叔丁基邻苯醌与亚锗烷基的氧化加成反应通过低价中心氧化成四价状态进行，并伴随着对称化形成相应的双邻氨基苯酚盐和锗（IV）的双（儿茶酚酸盐）衍生物。由起始亚锗烷 I 水解合成的二亚甲醚Ia在与镍环戊二烯基羰基二聚体反应中充当氧化剂并形成八元金属环，在化合物 (CpNi) 2 [ Ph AP-GeOGe