ethyl 2-deoxy-4-O-(α-D-glucopyranosyl)-1-thio-α/β-D-arabino-hexopyranoside | 1119275-91-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethyl 2-deoxy-4-O-(α-D-glucopyranosyl)-1-thio-α/β-D-arabino-hexopyranoside
• CAS: 1119275-91-0
• 化学式: C₁₄H₂₆O₉S
• 分子量: 370.421
• InChiKey: YIZPUKDCPXMYJA-MEUDHKOGSA-N

反应信息

• 作为反应物：
  描述：

  ethyl 2-deoxy-4-O-(α-D-glucopyranosyl)-1-thio-α/β-D-arabino-hexopyranoside 、 苯甲醛二甲缩醛 在 对甲苯磺酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 生成
  参考文献：
  名称：

  Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers

  摘要：

  Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenot, by a H-1 NMR method, showed complexation of the guest molecule with the host molecule. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2008.10.026