苯丙基溴化胺 | 120375-53-3

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯丙基溴化胺
• 英文名称: phenylpropylammonium bromide
• 英文别名: 3-phenylpropan-1-amine;hydrobromide
• CAS: 120375-53-3
• 化学式: Br*C₉H₁₄N
• 分子量: 216.121
• InChiKey: AKNWFTSJWORAMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.16
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  27.6
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯丙基溴化胺 、 manganese(ll) chloride 在 盐酸 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  具有不同长度芳胺阳离子的二维锰(II)基钙钛矿的光致发光性能

  摘要：

  有机阳离子的参与在调节广谱发射中起着重要作用。在此，我们合成了一系列具有不同长度芳胺阳离子的Mn(II)基二维(2D)卤化物钙钛矿，通式为(C 6 H 5 (CH 2 ) x NH 3 ) 2 MnCl 4 ( x = 1-4），这里首次报道了x = 4 化合物。随着-(CH 2)– 在有机阳离子中，相邻无机层之间的距离增加，导致标题化合物表现出不同的结构扭曲。随着 Mn-Cl-Mn 角畸变的增加，标题化合物的实验光学带隙相应增加。当化合物的八面体之间的角度畸变相似时，带隙也可能受到八面体本身畸变的影响（2的键长畸变大于4的键长畸变）。在 298 K 的紫外光照射下，所有化合物都表现出两个以 480-505 和 610 nm 为中心的发射峰，对应于有机阳离子发射和4 T 1 (G) 到6 A 1(S)分别是Mn 2+离子的辐射跃迁。在这些标题化合物中，(PPA) 2 MnCl 4 [(PPA)

  DOI：

  10.1021/acs.inorgchem.2c01730

文献信息

• PEROVSKITE THIN FILM AND PREPARATION METHOD THEREFOR, PEROVSKITE ELECTROLUMINESCENT DEVICE AND PREPARATION METHOD THEREFOR, AND DISPLAY DEVICE
  申请人：BOE TECHNOLOGY GROUP CO., LTD.

  公开号：EP3786259A1

  公开（公告）日：2021-03-03

  Provided are a perovskite film and method for manufacturing the same, a perovskite electroluminescent device and method for manufacturing the same, and a display device, which belongs to the technical field of displaying. The perovskite film comprises a crystalline perovskite and a halogenated amine ligand grafted onto the crystalline perovskite. Since the perovskite film comprises the halogenated amine ligand, the surface of the perovskite film is smooth, and the surface coverage of the crystalline perovskite is high without significant void defects. Meanwhile, the perovskite film also has a high fluorescence quantum yield due to the halogenated amine ligand comprised in the perovskite film.

  本发明提供了一种过氧化物薄膜及其制造方法、一种过氧化物电致发光装置及其制造方法以及一种显示装置，属于显示技术领域。该过氧化物薄膜包括晶体过氧化物和接枝到晶体过氧化物上的卤化胺配体。由于包晶薄膜包含卤化胺配体，因此包晶薄膜表面光滑，晶体包晶的表面覆盖率高，没有明显的空隙缺陷。同时，由于包晶膜中含有卤化胺配体，包晶膜还具有较高的荧光量子产率。
• Magnetic properties and critical behavior of quasi-two-dimensional systems [<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mrow><mml:mn>5</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CH</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mi mathvariant="italic">n</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">NH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mo>]</mml:mo></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CuBr</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>with<i>n</i>=1, 2, and 3
  作者：P. Zhou、John E. Drumheller、Baldev Patyal、R. D. Willett

  DOI：10.1103/physrevb.45.12365

  日期：——

  The magnetic properties and critical behavior of the quasi-two-dimensional ferromagnets [C6H5(CH2)n(NH3]2CuBr4, with n = 1, 2, and 3, have been studied. These compounds are typical of layered magnets in that they assume distorted layer perovskite structures in which copper(II) bromide layers are sheathed by the bulk organic cations. Magnetization and susceptibility measurements show strong ferromagnetic intralayer exchange of the order of 20-25 K with weak interlayer exchange coupling of less than 1 K. The magnetic anisotropies are explored through EPR-linewidth analysis. The critical exponent gamma and transition temperatures T(c) were determined by the measurements of ac initial susceptibility and isothermal magnetization. By employing a static scaling law to analyze the data of isothermal magnetizations near T(c), it was found that in a certain low-field and low-temperature region the powder magnetizations are suppressed so that the scaling hypothesis no longer holds. It is shown from the scaling analysis that the powder samples of these two-dimensional (2D) layer ferromagnets cannot be classified as simple ferromagnets whose critical behavior is described by the usual 2D critical theories.
• Zero-Dimensional Halides with ns² Electron (Sb³⁺) Activation to Generate Broad Photoluminescence
  作者：An Hou、Liubing Fan、Yan Xiong、Jiawei Lin、Kunjie Liu、Mingyue Chen、Zhongnan Guo、Jing Zhao、Quanlin Liu

  DOI：10.1021/acs.inorgchem.3c01726

  日期：2023.8.7
• QUATERNARY AMMONIUM COMPOUNDS AND THEIR USE AS ANTIMUSCARINIC AGENTS
  申请人：PHARMACIA & UPJOHN COMPANY

  公开号：EP1461306A1

  公开（公告）日：2004-09-29
• PEROVSKITE FILM AND METHOD FOR MANUFACTURING THE SAME, PEROVSKITE ELECTROLUMINESCENT DEVICE AND METHOD FOR MANUFACTURING THE SAME, AND DISPLAY DEVICE
  申请人：BOE Technology Group Co., Ltd.

  公开号：US20200255727A1

  公开（公告）日：2020-08-13

  Provided are a perovskite film and method for manufacturing the same, a. perovskite electroluminescent device and method for manufacturing the same, and a display device, which belongs to the technical field of displaying. The perovskite film comprises a crystalline perovskite and a halogenated amine ligand grafted onto the crystalline perovskite. Since the perovskite film comprises the halogenated amine ligand, the surface of the perovskite film is smooth, and the surface coverage of the crystalline perovskite is high without significant void defects. Meanwhile, the perovskite film also has a high fluorescence quantum yield due to the halogenated amine ligand comprised in the perovskite film.