bis(acetylacetonato-κ2O,O')[N,N'-bis(3-hydroxy-2-oxidobenzaldimino)-2-methyl-1,2-propanediamine-κ4N,O,O',N']uranium(IV) tetrahydrofuran solvate | 605666-14-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: bis(acetylacetonato-κ2O,O')[N,N'-bis(3-hydroxy-2-oxidobenzaldimino)-2-methyl-1,2-propanediamine-κ4N,O,O',N']uranium(IV) tetrahydrofuran solvate
• CAS: 605666-14-6
• 化学式: C₄H₈O*C₂₈H₃₂N₂O₈U
• 分子量: 834.707
• InChiKey: FQDQPDMPTJWZPZ-UKLQWGCTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 N,N'-bis(3-hydroxysalicylidene)-(2-methyl-1,3-propanediamine) 、 tetra(acetylacetonato)uranium(IV) 以 四氢呋喃 为溶剂， 以65%的产率得到bis(acetylacetonato-κ2O,O')[N,N'-bis(3-hydroxy-2-oxidobenzaldimino)-2-methyl-1,2-propanediamine-κ4N,O,O',N']uranium(IV) tetrahydrofuran solvate
  参考文献：
  名称：

  A bis(acetylacetonato)uranium(IV) complex of the Schiff baseN,N′-bis(3-hydroxysalicylidene)-2-methyl-1,2-propanediamine

  摘要：

  The title complex, bis(acetylacetonato-kappa(2)O,O')[N,N'-bis(3-hydroxy-2-oxidobenzaldimino)-2-methyl-1,2-propanediamine-kappa(4)N,O,O',N']uranium(IV) tetrahydrofuran solvate, [U(C18H18N2O4)(C5H7O2)(2)].C4H8O, is a rare example of a uranium(IV) complex with a compartmental Schiff base. The U atom is located in the N2O2 inner site of the hexadentate N,N'-bis(3-hydroxy-2-oxidobenzaldimino)-2-methyl-1,2-propanediamine group and is bound also to the two O atoms of both acetylacetonate moieties, which results in a dodecahedral coordination environment. Centrosymmetric dimers are formed through intermolecular hydrogen bonds that link the terminal uncoordinated hydroxy groups to one another and to the O atoms of the acetylacetonate ligands.

  DOI：

  10.1107/s0108270103008382