dimethyl 4-[(1,1-dimethylprop-2-ynyl)oxy]-4'methoxy[1,1'-biphenyl]-2,3-dicarboxylate | 268562-57-8

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: dimethyl 4-[(1,1-dimethylprop-2-ynyl)oxy]-4'methoxy[1,1'-biphenyl]-2,3-dicarboxylate
• 英文别名: Dimethyl 3-(4-methoxyphenyl)-6-(2-methylbut-3-yn-2-yloxy)benzene-1,2-dicarboxylate
• CAS: 268562-57-8
• 化学式: C₂₂H₂₂O₆
• 分子量: 382.413
• InChiKey: ZAUJXWGDTGKELN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  dimethyl 4-[(1,1-dimethylprop-2-ynyl)oxy]-4'methoxy[1,1'-biphenyl]-2,3-dicarboxylate 以 N,N-二甲基苯胺 、 N,N-二甲基甲酰胺 为溶剂， 以50%的产率得到dimethyl 2,2-dimethyl-6-(4-methoxyphenyl)-2H-chromene-7,8-dicarboxylate
  参考文献：
  名称：

  Synthesis and Spectrokinetic Studies of a New Family of Dimethyl [2H]-Chromenes: Dimethyl 6-Aryl-2,2Dimethyl-[2H]-Chromene-7,8-Dicarboxylates

  摘要：

  The synthesis of a series of dimethyl 6-aryl-2,2-dimethyl-[2H]-chromene-7,8-dicarboxylates is described. The photochromic properties of this new family of dimethyl-[2H]-chromenes have been studied in solution, under continuous irradiation. The presence of the methoxycarbonyl groups was shown to stabilise the coloured forms. The fading rates are generally low in comparison with the standard "naked" chromenes in the same experimental conditions. This stabilisation depends on the solvent used. We could observe the presence of one permanent opened form. Moreover, it seems that the synthesised molecules have a strong resistance toward photodegradation.

  DOI：

  10.1080/10587250008023846
• 作为产物：
  描述：

  (8CI)-2-(p-甲氧基苯基)-呋喃 在 zinc(II) iodide copper(l) iodide 、 potassium carbonate 、 potassium iodide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 生成 dimethyl 4-[(1,1-dimethylprop-2-ynyl)oxy]-4'methoxy[1,1'-biphenyl]-2,3-dicarboxylate
  参考文献：
  名称：

  Synthesis and Spectrokinetic Studies of a New Family of Dimethyl [2H]-Chromenes: Dimethyl 6-Aryl-2,2Dimethyl-[2H]-Chromene-7,8-Dicarboxylates

  摘要：

  The synthesis of a series of dimethyl 6-aryl-2,2-dimethyl-[2H]-chromene-7,8-dicarboxylates is described. The photochromic properties of this new family of dimethyl-[2H]-chromenes have been studied in solution, under continuous irradiation. The presence of the methoxycarbonyl groups was shown to stabilise the coloured forms. The fading rates are generally low in comparison with the standard "naked" chromenes in the same experimental conditions. This stabilisation depends on the solvent used. We could observe the presence of one permanent opened form. Moreover, it seems that the synthesised molecules have a strong resistance toward photodegradation.

  DOI：

  10.1080/10587250008023846

文献信息

• ——
  作者：Alain Maggiani、Arlette Tubul、Pierre Brun

  DOI：10.1002/(sici)1522-2675(20000315)83:3<650::aid-hlca650>3.0.co;2-u

  日期：2000.3.15

  A series of dimethyl 6-aryl-2,2dimethyl-2N-chromene-7,8-dicarboxylates were synthesized, and the photochromic properties of this new family of dimethyl-2H-chromenes were studied under continuous irradiation. The presence of the methoxycarbonyl groups was shown to stabilize the colored forms. This stabilization depended on the solvent, and in two cases the formation of long-lived opened forms was observed. Under irradiation with a mercury lamp, this family of 2H-chromenes showed a strong resistance: to photodegradation.