Acetic acid (3aS,6R,6aR,7S,8R,9R,9aS,9bR)-8-acetoxy-6,6a,9-trihydroxy-6,9-dimethyl-3-methylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-7-yl ester | 137606-45-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Acetic acid (3aS,6R,6aR,7S,8R,9R,9aS,9bR)-8-acetoxy-6,6a,9-trihydroxy-6,9-dimethyl-3-methylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-7-yl ester
• CAS: 137606-45-2
• 化学式: C₁₉H₂₆O₉
• 分子量: 398.41
• InChiKey: PUPKZGUFHUDDPU-NBZYPENOSA-N

反应信息

• 作为产物：
  描述：

  乙酸酐 、 1α,2α,3α,4β,10α-Pentahydroxyguaia-11(13)ene-12,6α-olide 反应 5.0h， 以4 mg的产率得到Acetic acid (3aS,6R,6aR,7S,8R,9R,9aS,9bR)-8-acetoxy-6,6a,9-trihydroxy-6,9-dimethyl-3-methylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-7-yl ester
  参考文献：
  名称：

  Sesquiterpene lactones from Artemisia rutifolia

  摘要：

  Continuous phytochemical investigation of the aerial parts of Artemisia rutifolia afforded further, in addition to several known compounds, two new highly oxygenated guaianolides and three seco-guaianolides. The structures were elucidated by high field NMR techniques and a few chemical transformations.

  DOI：

  10.1016/s0031-9422(00)98246-3