(1RS,1'RS,3aSR,4SR,5SR,7aSR)-1-(1',5'-dimethylhexyl)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-7a-methyloctahydro-1H-inden-5-ol | 122334-34-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1RS,1'RS,3aSR,4SR,5SR,7aSR)-1-(1',5'-dimethylhexyl)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-7a-methyloctahydro-1H-inden-5-ol
• CAS: 122334-34-3
• 化学式: C₂₃H₄₂O₃
• 分子量: 366.585
• InChiKey: PGUGDNZDGUVCKL-IBYACTMASA-N

反应信息

• 作为产物：
  描述：

  (1RS,1'RS,3aSR,4SR,5SR,7aRS)-1-(1',5'-dimethylhexa-3',5'-dienyl)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-7a-methyloctahydro-1H-inden-5-ol 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以97%的产率得到(1RS,1'RS,3aSR,4SR,5SR,7aSR)-1-(1',5'-dimethylhexyl)-4-<(1''',3'''-dioxan-2'''-yl)methyl>-7a-methyloctahydro-1H-inden-5-ol
  参考文献：
  名称：

  Use of .beta.-sulfonyl vinyl ketones as equivalents to vinyl ketones in the Robinson annelation. Convergent, highly stereoselective preparation of a hydrindanol related to vitamin D from 2-methylcyclopent-2-enone and lithiated (E)-but-2-enyldiphenylphosphine oxide

  摘要：

  DOI：

  10.1021/jo00282a038