(R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid 2-((1R,4R)-4-methyl-3-oxo-cyclohexyl)-propyl ester | 140860-30-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid 2-((1R,4R)-4-methyl-3-oxo-cyclohexyl)-propyl ester
• CAS: 140860-30-6
• 化学式: C₂₀H₂₅F₃O₄
• 分子量: 386.411
• InChiKey: RUIUHBLKHCREOL-IEUGYZJKSA-N

反应信息

• 作为产物：
  描述：

  Acetic acid 2-((1R,3S,4R)-3-hydroxy-4-methyl-cyclohexyl)-propyl ester 在 吡啶 、 氢氧化钾 、 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 16.0h， 生成 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid 2-((1R,4R)-4-methyl-3-oxo-cyclohexyl)-propyl ester
  参考文献：
  名称：

  Biotransformation of monoterpenoids, (−)- and menthols, terpinolene and carvotanacetone by Aspergillus species

  摘要：

  Four monoterpenoids. (-)- and (+)-menthols, terpinolene and carvotanacetone were biotransformed by Aspergillus niger and several related species. Aspergillus niger converted (-)-menthol to 1-, 2-, 6-, 7-, and 9-hydroxymenthols and the mosquito repellent-active 8-hydroxymenthol. On the other hand, (+)-menthol was smoothly biotransformed by A. niger to give 7-hydroxymenthol. Aspergillus cellulosae biotransformed (-)-menthol specifically to 4-hydroxymenthol. Terpinolene and (-)-carvotanacetone were converted by A. niger to two alpha,beta-unsaturated ketones, a fenchane-type compound and diastereoisomeric p-menthane-2,9-diols and 8-hydroxycarvomenthol, respectively.

  DOI：

  10.1016/0031-9422(91)83449-u