(2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-hexadecyloxymethyl-6-methoxy-tetrahydro-pyran | 142025-35-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-hexadecyloxymethyl-6-methoxy-tetrahydro-pyran
• CAS: 142025-35-2
• 化学式: C₄₄H₆₄O₆
• 分子量: 688.989
• InChiKey: WENDNSAMFQZYEC-IYFSMEFCSA-N

反应信息

• 作为反应物：
  描述：

  (2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-hexadecyloxymethyl-6-methoxy-tetrahydro-pyran 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 为溶剂， 生成 (2R,3S,4S,5R,6S)-2-Hexadecyloxymethyl-6-methoxy-tetrahydro-pyran-3,4,5-triol
  参考文献：
  名称：

  Amphiphilic and mesogenic carbohydrates - II. sysnthesis and Characterisation of mono-o-(n-alkyl)-d-glucose derivates

  摘要：

  The synthesis of various amphiphilic o-(n-alkyl)-D-glucopyranoses, having the long alkyl chain (C8H17 - C16H33) in 2-, 3-, 4- or 6-position are described. The investigations of the thermal behaviour of 6-o-(13a-e), 4-o-(14a-e), 3-o-(15a-e) and 2-o-(n-alkyl)-D-glucopyranoses (16a-e) and the corresponding methyl-alpha-D-glucosides 4a-e, 8a-e and 12a-e, respectively, are summarized in this paper.

  DOI：

  10.1016/s0040-4020(01)92248-3
• 作为产物：
  描述：

  甲基2,3,4-三-O-苄基-α-D-吡喃葡萄糖苷 、 溴代十六烷 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 (2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-hexadecyloxymethyl-6-methoxy-tetrahydro-pyran
  参考文献：
  名称：

  Amphiphilic and mesogenic carbohydrates - II. sysnthesis and Characterisation of mono-o-(n-alkyl)-d-glucose derivates

  摘要：

  The synthesis of various amphiphilic o-(n-alkyl)-D-glucopyranoses, having the long alkyl chain (C8H17 - C16H33) in 2-, 3-, 4- or 6-position are described. The investigations of the thermal behaviour of 6-o-(13a-e), 4-o-(14a-e), 3-o-(15a-e) and 2-o-(n-alkyl)-D-glucopyranoses (16a-e) and the corresponding methyl-alpha-D-glucosides 4a-e, 8a-e and 12a-e, respectively, are summarized in this paper.

  DOI：

  10.1016/s0040-4020(01)92248-3