2-O-<2-acetamido-4-O-<2-acetamido-4-O-((5S)-5-carbamoyl-β-L-arabinopyranosyl)-2,6-dideoxy-β-D-glucopyranosyl>-2,6-dideoxy-β-D-glucopyranosyl>-3-O-carbamoyl-1-O-<<(R)-2-carboxy-2-(3,8,8,11,14,18-hexamethyl-nonadecyloxy)-ethoxy>-hydroxyphosphoryl>-... | 152554-21-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-O-<2-acetamido-4-O-<2-acetamido-4-O-((5S)-5-carbamoyl-β-L-arabinopyranosyl)-2,6-dideoxy-β-D-glucopyranosyl>-2,6-dideoxy-β-D-glucopyranosyl>-3-O-carbamoyl-1-O-<<(R)-2-carboxy-2-(3,8,8,11,14,18-hexamethyl-nonadecyloxy)-ethoxy>-hydroxyphosphoryl>-...
• CAS: 152554-21-7
• 化学式: C₅₇H₁₀₂N₅O₂₆P
• 分子量: 1304.43
• InChiKey: ZZJWKYNOQGANCX-CVNATWERSA-N

反应信息

• 作为反应物：
  描述：

  2-O-<2-acetamido-4-O-<2-acetamido-4-O-((5S)-5-carbamoyl-β-L-arabinopyranosyl)-2,6-dideoxy-β-D-glucopyranosyl>-2,6-dideoxy-β-D-glucopyranosyl>-3-O-carbamoyl-1-O-<<(R)-2-carboxy-2-(3,8,8,11,14,18-hexamethyl-nonadecyloxy)-ethoxy>-hydroxyphosphoryl>-... 在 ammonium hydroxide 、 sodium periodate 、 硫酸 、 sodium acetate 、 溶剂黄146 、 偏二甲肼 作用下， 反应 58.0h， 生成 2-O-(2-acetamido-2,6-dideoxy-β-D-glucopyranosyl)-3-O-carbamoyl-1-O-<<(R)-2-carboxy-2-(3,8,8,11,14,18-hexamethyl-nonadecyloxy)-ethoxy>-hydroxyphosphoryl>-α-D-galactopyranuronamide
  参考文献：
  名称：

  The first moenomycin antibiotic without the methyl-branched uronic acid constituent.- Unexpected structure activity relations

  摘要：

  Isolation and structure elucidation of a new moenomycin antibiotic (C1, 1e) that lacks the branching methyl group in the 4-position of unit F are reported. The smallest antibiotically active degradation product of le is the trisaccharide derivative 3. This observation is in contrast to structure activity relations in the moenomycin A series where it was found that disaccharide 4a is fully active.

  DOI：

  10.1016/s0040-4020(01)87242-2
• 作为产物：
  描述：

  decahydromoenomycin C1 在 potassium carbonate 、 potassium hexacyanoferrate(III) 作用下， 以 水 为溶剂， 以100%的产率得到2-O-<2-acetamido-4-O-<2-acetamido-4-O-((5S)-5-carbamoyl-β-L-arabinopyranosyl)-2,6-dideoxy-β-D-glucopyranosyl>-2,6-dideoxy-β-D-glucopyranosyl>-3-O-carbamoyl-1-O-<<(R)-2-carboxy-2-(3,8,8,11,14,18-hexamethyl-nonadecyloxy)-ethoxy>-hydroxyphosphoryl>-...
  参考文献：
  名称：

  The first moenomycin antibiotic without the methyl-branched uronic acid constituent.- Unexpected structure activity relations

  摘要：

  Isolation and structure elucidation of a new moenomycin antibiotic (C1, 1e) that lacks the branching methyl group in the 4-position of unit F are reported. The smallest antibiotically active degradation product of le is the trisaccharide derivative 3. This observation is in contrast to structure activity relations in the moenomycin A series where it was found that disaccharide 4a is fully active.

  DOI：

  10.1016/s0040-4020(01)87242-2