catena-poly([aqua(1,10-phenanthroline-κ2-N,N')cobalt(II)]-μ-benzene-1,4-dicarboxylato-κ2-O1:O4) | 375364-96-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: catena-poly([aqua(1,10-phenanthroline-κ2-N,N')cobalt(II)]-μ-benzene-1,4-dicarboxylato-κ2-O1:O4)
• CAS: 375364-96-8；1000676-19-6
• 化学式: C₂₀H₁₄CoN₂O₅
• 分子量: 421.335
• InChiKey: JWUZPJISNMFCSZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 对苯二甲酸 、 disodium terephthalate 、 cobalt(II) nitrate 以 水 、 二甲基亚砜 为溶剂， 生成 catena-poly([aqua(1,10-phenanthroline-κ2-N,N')cobalt(II)]-μ-benzene-1,4-dicarboxylato-κ2-O1:O4)
  参考文献：
  名称：

  Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C₈H₄O₄)(C₁₂H₈N₂)(H₂O)] and [Cu(C₈H₄O₄)(C₁₀H₉N₃)]·H₂O

  摘要：

  The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.

  DOI：

  10.1107/s0108270102004341