(4S,4aS,5R,6aS,6bR,8aR,9R,10S,12aR,12bR,14bS)-4,5,10-Trihydroxy-9-hydroxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carbaldehyde | 145940-89-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (4S,4aS,5R,6aS,6bR,8aR,9R,10S,12aR,12bR,14bS)-4,5,10-Trihydroxy-9-hydroxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carbaldehyde
• CAS: 145940-89-2
• 化学式: C₃₀H₄₈O₅
• 分子量: 488.708
• InChiKey: SULCCLHANCZVIS-CUCCWGAISA-N

反应信息

• 作为反应物：
  描述：

  (4S,4aS,5R,6aS,6bR,8aR,9R,10S,12aR,12bR,14bS)-4,5,10-Trihydroxy-9-hydroxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carbaldehyde 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 0.33h， 以3.5 mg的产率得到山茶皂苷元C
  参考文献：
  名称：

  Two oleanane triterpenes from Anagallis arvensis

  摘要：

  Two new triterpenes, have been isolated from the weed Anagallis arvensis. Their structures, strictly related to that of an oleanane metabolite previously isolated from the same source, have been established on the basis of spectral analyses and chemical correlation with camelliagenin C, a triterpene from Camellia sp.

  DOI：

  10.1016/s0031-9422(00)97564-2
• 作为产物：
  描述：

  (1S,2R,4S,5R,8R,9R,10S,13R,14R,17S,18R,22S)-9-(hydroxymethyl)-4,5,9,13,20,20-hexamethyl-24-oxahexacyclo[15.5.2.01,18.04,17.05,14.08,13]tetracosane-2,10,22-triol 在 盐酸 作用下， 以 1,4-二氧六环 为溶剂， 反应 1.0h， 以2.5 mg的产率得到(4S,4aS,5R,6aS,6bR,8aR,9R,10S,12aR,12bR,14bS)-4,5,10-Trihydroxy-9-hydroxymethyl-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-octadecahydro-2H-picene-4a-carbaldehyde
  参考文献：
  名称：

  Two oleanane triterpenes from Anagallis arvensis

  摘要：

  Two new triterpenes, have been isolated from the weed Anagallis arvensis. Their structures, strictly related to that of an oleanane metabolite previously isolated from the same source, have been established on the basis of spectral analyses and chemical correlation with camelliagenin C, a triterpene from Camellia sp.

  DOI：

  10.1016/s0031-9422(00)97564-2