bis(1,10-phenanthroline)(9,10-diamino-1,4,5,8-tetraazaphenanthrene)ruthenium(II) | 868588-14-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: bis(1,10-phenanthroline)(9,10-diamino-1,4,5,8-tetraazaphenanthrene)ruthenium(II)
• 英文别名: [Ru(phen)2(diamino-TAP)](2+)
• CAS: 868588-14-1
• 化学式: C₃₄H₂₄N₁₀Ru
• 分子量: 673.702
• InChiKey: PECVYCKVFGRDOE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 bis(1,10-phenanthroline)(9,10-diamino-1,4,5,8-tetraazaphenanthrene)ruthenium(II) 以 乙醇 、 水 、 溶剂黄146 为溶剂， 以67%的产率得到bis(1,10-phenanthroline)(1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene)ruthenium(II) bis(hexafluorophosphate)
  参考文献：
  名称：

  [Ru(phen)₂(PHEHAT)]²⁺ and [Ru(phen)₂(HATPHE)]²⁺: Two Ruthenium(II) Complexes with the Same Ligands but Different Photophysics and Spectroelectrochemistry

  摘要：

  The properties of two mononuclear Ru(II) complexes formed with the extended planar ligand PHEHAT depend drastically on the chelation site by the metallic ion. When the chelation takes place on the HAT site of the ligand (case of the novel complex [Ru(phen)(2)(HATPHE)](2+)), the emission behavior is quite similar to that of (Ru(phen)(2)(HAT)](2+). In contrast, when the chelation is on the phen motif of the ligand (case of [Ru(phen)(2)(PHEHAT)](2+)), the spectroscopic (absorption and emission) and electrochemical data for the complex do not obey the linear spectroelectrochemical correlation and the emission behavior is comparable to that of the extensively studied dppz complex ([Ru(phen/bpy)(2)(dppZ)](2+)), Thus, for [Ru(phen)(2)(PHEHAT)](2+), the emission lifetimes and intensities as a function of temperature exhibit a maximum for nitrile solvents. However, in contrast to the dppz case, at least three different states (two emitting and one dark) participate in the deactivation with different contributions depending on the temperature. These different contributions explain the observed maximum. Moreover, the fact that the solvent is liquid or frozen also influences the nature of the luminescent species.

  DOI：

  10.1021/ic051306f
• 作为产物：
  描述：

  Ru(phen)₂Cl₂ 、 9,10-diamino-1,4,5,8-tetraazaphenanthrene 以 乙醇 、 水 为溶剂， 以46%的产率得到bis(1,10-phenanthroline)(9,10-diamino-1,4,5,8-tetraazaphenanthrene)ruthenium(II)
  参考文献：
  名称：

  [Ru(phen)₂(PHEHAT)]²⁺ and [Ru(phen)₂(HATPHE)]²⁺: Two Ruthenium(II) Complexes with the Same Ligands but Different Photophysics and Spectroelectrochemistry

  摘要：

  The properties of two mononuclear Ru(II) complexes formed with the extended planar ligand PHEHAT depend drastically on the chelation site by the metallic ion. When the chelation takes place on the HAT site of the ligand (case of the novel complex [Ru(phen)(2)(HATPHE)](2+)), the emission behavior is quite similar to that of (Ru(phen)(2)(HAT)](2+). In contrast, when the chelation is on the phen motif of the ligand (case of [Ru(phen)(2)(PHEHAT)](2+)), the spectroscopic (absorption and emission) and electrochemical data for the complex do not obey the linear spectroelectrochemical correlation and the emission behavior is comparable to that of the extensively studied dppz complex ([Ru(phen/bpy)(2)(dppZ)](2+)), Thus, for [Ru(phen)(2)(PHEHAT)](2+), the emission lifetimes and intensities as a function of temperature exhibit a maximum for nitrile solvents. However, in contrast to the dppz case, at least three different states (two emitting and one dark) participate in the deactivation with different contributions depending on the temperature. These different contributions explain the observed maximum. Moreover, the fact that the solvent is liquid or frozen also influences the nature of the luminescent species.

  DOI：

  10.1021/ic051306f