((4-((4-cyanophenyl)ethynyl)phenyl)ethynyl)(triphenyl-l5-phosphaneyl)gold | 1022138-74-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((4-((4-cyanophenyl)ethynyl)phenyl)ethynyl)(triphenyl-l5-phosphaneyl)gold
• CAS: 1022138-74-4
• 化学式: C₃₅H₂₃AuNP
• 分子量: 685.515
• InChiKey: IMRNBZVTVQXXPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Ru3(CO)10(μ-bis(diphenylphosphino)methane) 、 ((4-((4-cyanophenyl)ethynyl)phenyl)ethynyl)(triphenyl-l5-phosphaneyl)gold 以 四氢呋喃 为溶剂， 生成 [Ru3(μ-AuPPh3)(μ-C2C6H4C2C6H4CN)(CO)(μ-dppm)]
  参考文献：
  名称：

  The syntheses, structures and redox properties of phosphine-gold(I) and triruthenium-carbonyl cluster derivatives of tolans

  摘要：

  The syntheses of several ethynyl-gold(I) phosphine substituted tolans (1,2-diaryl acetylenes) of general form [Au(C=CC6H4C=CC6H4X)(PPh3)] are described [X = Me (2a), OMe (2b), CO2Me (2c), NO2 (2d), CN (2e)]. These complexes react readily with [Ru-3(CO) 10(mu-dppm)] to give the heterometallic clusters [Ru3(mu-AuPPh3)(mu-eta(1), eta(2)-C2C6H4C, CC6H4X)(CO)(7)(mu-dppm)] (3a-e). The crystallographically determined molecular structures of 2b, 2d, 2e and 3a-e are reported here, that of 2a having been described on a previous occasion. Structural, spectroscopic and electrochemical studies were conducted and have revealed little electronic interaction between the remote substituent and the organometallic end-caps. (C) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.03.032
• 作为产物：
  描述：

  三苯基膦氯金 、 1-trimethylsilylethynyl-4-((4-cyanophenyl)-ethynyl)benzene 在 NaOH 作用下， 以 甲醇 为溶剂， 以71%的产率得到((4-((4-cyanophenyl)ethynyl)phenyl)ethynyl)(triphenyl-l5-phosphaneyl)gold
  参考文献：
  名称：

  The syntheses, structures and redox properties of phosphine-gold(I) and triruthenium-carbonyl cluster derivatives of tolans

  摘要：

  The syntheses of several ethynyl-gold(I) phosphine substituted tolans (1,2-diaryl acetylenes) of general form [Au(C=CC6H4C=CC6H4X)(PPh3)] are described [X = Me (2a), OMe (2b), CO2Me (2c), NO2 (2d), CN (2e)]. These complexes react readily with [Ru-3(CO) 10(mu-dppm)] to give the heterometallic clusters [Ru3(mu-AuPPh3)(mu-eta(1), eta(2)-C2C6H4C, CC6H4X)(CO)(7)(mu-dppm)] (3a-e). The crystallographically determined molecular structures of 2b, 2d, 2e and 3a-e are reported here, that of 2a having been described on a previous occasion. Structural, spectroscopic and electrochemical studies were conducted and have revealed little electronic interaction between the remote substituent and the organometallic end-caps. (C) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.03.032