(1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-1-((2S,3R,4S)-3,4-diacetoxy-6-formyl-3,4-dihydro-2H-pyran-2-yloxy)-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester | 273200-98-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-1-((2S,3R,4S)-3,4-diacetoxy-6-formyl-3,4-dihydro-2H-pyran-2-yloxy)-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester
• CAS: 273200-98-9
• 化学式: C₃₃H₃₆O₁₅
• 分子量: 672.64
• InChiKey: APLMRJKULFLJLS-XVQYRNPUSA-N

反应信息

• 作为反应物：
  描述：

  (1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-1-((2S,3R,4S)-3,4-diacetoxy-6-formyl-3,4-dihydro-2H-pyran-2-yloxy)-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester 在 sodium tetrahydroborate 、 Amberlite IR 120 作用下， 以 甲醇 为溶剂， 反应 0.75h， 以87%的产率得到(1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-1-((2S,3R,4S)-3,4-diacetoxy-6-hydroxymethyl-3,4-dihydro-2H-pyran-2-yloxy)-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester
  参考文献：
  名称：

  Raj; Mathad, Vijayavitthal T.; Bhaduri, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 10, p. 1056 - 1061

  摘要：

  DOI：
• 作为产物：
  描述：

  (1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester 在 pyridinium chlorochromate 作用下， 以 苯 为溶剂， 以58%的产率得到(1S,4aS,5S,6R,7R,7aR)-5-Acetoxy-1-((2S,3R,4S)-3,4-diacetoxy-6-formyl-3,4-dihydro-2H-pyran-2-yloxy)-6-[(E)-3-(4-methoxy-phenyl)-acryloyloxy]-7-methyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid methyl ester
  参考文献：
  名称：

  Raj; Mathad, Vijayavitthal T.; Bhaduri, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 10, p. 1056 - 1061

  摘要：

  DOI：