2-(3,3-Diphenylbenzo[f]chromen-8-yl)oxyethanol | 1416437-17-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: 2-(3,3-Diphenylbenzo[f]chromen-8-yl)oxyethanol
• 英文别名: 2-(3,3-diphenylbenzo[f]chromen-8-yl)oxyethanol
• CAS: 1416437-17-6
• 化学式: C₂₇H₂₂O₃
• 分子量: 394.47
• InChiKey: WJDJVXMIBJLOGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(3,3-Diphenylbenzo[f]chromen-8-yl)oxyethanol 在 四溴化碳 、 potassium carbonate 、 三苯基膦 、 potassium iodide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 49.0h， 生成
  参考文献：
  名称：

  Systemic study on fluorescent switching systems composed of naphthopyran and benzimidazole in solution and film forms

  摘要：

  The fluorescent photo-switching systems were prepared based on fluorescent benzimidazole and photochromic naphthopyran. Naphthopyran in this systems displayed excellent photochromic performance in tetrahydrofuran solutions and in PMMA films. The fluorescent emission of benzimidazole was modulated between "on" and "off" via the photoisomerization of naphthopyran in high-contrast due to the photoinduced energy transfer from benzimidazole to the open-form naphthopyran. Both the fluorescent photoswitching and the photochromism of benzimidazole-naphthopyran dyads in solutions and films displayed excellent fatigue resistance. The spaces between benzimidazole and naphthopyran affect the absorbance and fluorescence spectra of benzimidazole-naphthopyran dyads. The non-destructive readout ability of synthesized dyads in doped PMMA film was achieved. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2016.03.031
• 作为产物：
  描述：

  2,6-萘二酚 在 potassium carbonate 、 对甲苯磺酸 、 potassium iodide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 2-(3,3-Diphenylbenzo[f]chromen-8-yl)oxyethanol
  参考文献：
  名称：

  调制萘并吡喃光致变色：一种微乳液共聚策略

  摘要：

  通过与甲基丙烯酸甲酯（MMA）和甲基丙烯酸正丁酯（BMA）单体进行细乳液共聚制备了新型的基于萘并吡喃衍生物的光致变色聚合物纳米粒子。光致变色速率的系统的调制可以实现经由调整MMA和BMA单体的比例，以使萘并吡喃在刚性和柔软的环境之间摇摆。透射电子显微照片（TEM）和动态光散射（DLS）图像证明纳米颗粒是离散且光滑的。聚合物纳米颗粒中萘并吡喃的典型光谱特征表明，光致色素成功地掺入了纳米颗粒中。另外，该聚合物纳米颗粒在UV辐射和热逆反应时显示出良好的光致变色可逆性和稳定性。

  DOI：

  10.1039/c3nj01313h

文献信息

• Toward modulation of the naphthopyran photochromism: a miniemulsion copolymerization strategy
  作者：Dehua Li、Meiduo Zhang、Guang Wang、Shuangxi Xing

  DOI：10.1039/c3nj01313h

  日期：——

  Novel naphthopyran derivative based photochromic polymer nanoparticles are prepared via miniemulsion copolymerization with methyl methacrylate (MMA) and n-butyl methacrylate (BMA) monomers. The systematic modulation of the photochromic rate can be achieved via tuning the ratio of MMA and BMA monomers to lead the naphthopyrans to swing between rigid and soft surroundings. Transmission electron micrographs

  通过与甲基丙烯酸甲酯（MMA）和甲基丙烯酸正丁酯（BMA）单体进行细乳液共聚制备了新型的基于萘并吡喃衍生物的光致变色聚合物纳米粒子。光致变色速率的系统的调制可以实现经由调整MMA和BMA单体的比例，以使萘并吡喃在刚性和柔软的环境之间摇摆。透射电子显微照片（TEM）和动态光散射（DLS）图像证明纳米颗粒是离散且光滑的。聚合物纳米颗粒中萘并吡喃的典型光谱特征表明，光致色素成功地掺入了纳米颗粒中。另外，该聚合物纳米颗粒在UV辐射和热逆反应时显示出良好的光致变色可逆性和稳定性。
• Systemic study on fluorescent switching systems composed of naphthopyran and benzimidazole in solution and film forms
  作者：Yi He、Guang Wang、Mingxin Wang

  DOI：10.1016/j.molstruc.2016.03.031

  日期：2016.7

  The fluorescent photo-switching systems were prepared based on fluorescent benzimidazole and photochromic naphthopyran. Naphthopyran in this systems displayed excellent photochromic performance in tetrahydrofuran solutions and in PMMA films. The fluorescent emission of benzimidazole was modulated between "on" and "off" via the photoisomerization of naphthopyran in high-contrast due to the photoinduced energy transfer from benzimidazole to the open-form naphthopyran. Both the fluorescent photoswitching and the photochromism of benzimidazole-naphthopyran dyads in solutions and films displayed excellent fatigue resistance. The spaces between benzimidazole and naphthopyran affect the absorbance and fluorescence spectra of benzimidazole-naphthopyran dyads. The non-destructive readout ability of synthesized dyads in doped PMMA film was achieved. (C) 2016 Elsevier B.V. All rights reserved.