2,4,6-Tris(5-ethynylthiophen-2-yl)-1,3,5-triazine | 1449693-96-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 2,4,6-Tris(5-ethynylthiophen-2-yl)-1,3,5-triazine
• 英文别名: 2,4,6-tris(5-ethynylthiophen-2-yl)-1,3,5-triazine
• CAS: 1449693-96-2
• 化学式: C₂₁H₉N₃S₃
• 分子量: 399.521
• InChiKey: JNNXPDVHZTXOKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  123
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4,6-Tris(5-ethynylthiophen-2-yl)-1,3,5-triazine 、 4-iodo-1-(ferrocenyl)ethynylbenzene 在 四(三苯基膦)钯 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 以32%的产率得到
  参考文献：
  名称：

  Donor–acceptor ferrocenyl triazines: synthesis and properties

  摘要：

  A series of star shaped donor-pi-acceptor type symmetrical triazine was designed and synthesized by the Pd-catalysed Sonogshira cross coupling reaction. The ferrocenyl moiety with different spacer groups acts as donor and 1,3,5-triazine as acceptor. The photophysical results show intramolecular charge transfer from ferrocene to the 1,3,5-triazine unit. The cyclic voltammetric analysis reveals substantial donor-acceptor interaction. The triazines exhibit good thermal stability with high decomposition temperature. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.07.119
• 作为产物：
  描述：

  2,4,6-三(5-溴噻吩-2-基)-1,3,5-三嗪 在 甲醇 、 sodium hydroxide 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以68%的产率得到2,4,6-Tris(5-ethynylthiophen-2-yl)-1,3,5-triazine
  参考文献：
  名称：

  Donor–acceptor ferrocenyl triazines: synthesis and properties

  摘要：

  A series of star shaped donor-pi-acceptor type symmetrical triazine was designed and synthesized by the Pd-catalysed Sonogshira cross coupling reaction. The ferrocenyl moiety with different spacer groups acts as donor and 1,3,5-triazine as acceptor. The photophysical results show intramolecular charge transfer from ferrocene to the 1,3,5-triazine unit. The cyclic voltammetric analysis reveals substantial donor-acceptor interaction. The triazines exhibit good thermal stability with high decomposition temperature. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.07.119

文献信息

• Donor–acceptor ferrocenyl triazines: synthesis and properties
  作者：Ramesh Maragani、Rajneesh Misra

  DOI：10.1016/j.tetlet.2013.07.119

  日期：2013.9

  A series of star shaped donor-pi-acceptor type symmetrical triazine was designed and synthesized by the Pd-catalysed Sonogshira cross coupling reaction. The ferrocenyl moiety with different spacer groups acts as donor and 1,3,5-triazine as acceptor. The photophysical results show intramolecular charge transfer from ferrocene to the 1,3,5-triazine unit. The cyclic voltammetric analysis reveals substantial donor-acceptor interaction. The triazines exhibit good thermal stability with high decomposition temperature. (c) 2013 Elsevier Ltd. All rights reserved.