2-methyl-4-eicosanoxy-5-isopropylaniline | 865437-86-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-methyl-4-eicosanoxy-5-isopropylaniline
• 英文别名: 4-icosoxy-2-methyl-5-propan-2-ylaniline
• CAS: 865437-86-1
• 化学式: C₃₀H₅₅NO
• 分子量: 445.773
• InChiKey: VEGZVDKNVGDKOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.6
• 重原子数：
  32
• 可旋转键数：
  21
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-4-eicosanoxy-5-isopropylaniline 、 2,6-二乙酰基吡啶 、 2,6-Bis[1-(4-eicosanoxy-2-methylphenylimino)ethyl]pyridine 以 甲苯 为溶剂， 反应 20.0h， 生成 2,6-Bis[1-(2-methyl-4-eicosanoxy-5-isopropylphenylimino)ethyl]pyridine
  参考文献：
  名称：

  Transition metal complexes

  摘要：

  这是一种过渡金属配合物，其为双芳基亚胺吡啶MXn配合物或[bis-芳基亚胺吡啶MXp+][NC−]q配合物，包括一个双芳基亚胺吡啶配体和M为一种过渡金属原子；n匹配过渡金属原子M的形式氧化态；X为卤素，可选取代的烃基，醇酸盐，酰胺或氢化物；NC−为非配位阴离子；p+q匹配过渡金属原子M的形式氧化态。本发明的过渡金属配合物及其与非配位阴离子的配合物和含有这种配合物的催化体系在非极性介质和化学惰性的非极性溶剂，尤其是芳香烃溶剂中具有良好的溶解性。该催化体系可用于广泛的(共)寡聚、聚合和二聚反应。

  公开号：

  US20050215792A1

文献信息

• [EN] TRANSITION METAL COMPLEXES<br/>[FR] TRANSITION METAL COMPLEXES
  申请人：SHELL INT RESEARCH

  公开号：WO2005090371A1

  公开（公告）日：2005-09-29

  A transition metal complex which is a bis-arylimine pyridine MXn complex, comprising a bis-arylimine pyridine ligand having the formula (I), wherein R1-R5, R7-R9, R12 and R14 are each, independently, hydrogen, optionally substituted hydrocarbyl, an inert functional group, or any two of R1-R3 and R7-R9 vicinal to one another taken together may form a ring, and R6 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R7 or R4 to form a ring, R10 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R9 or R4 to form a ring, R11 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R12 or R5 to form a ring, R15 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R14 or R5 to form a ring, provided that R13 and at least one of R12 and R14 are independently selected from optionally substituted C1-C30 alkyl, optionally substituted C4-C30 alkyloxy, halogen and optionally substituted C5-C20 aryl, or R13 taken together with R12 or R14 form a ring, or R12 taken together with R11 form a ring and R14 taken together with R15 form a ring, and provided that at least one of R12, R13 and R14 is optionally substituted C4-C30 alkyloxy; M is a transition metal atom in particular selected from Ti, V, Cr, Mn, Fe, Co, Ni, Pd, Rh, Ru, Mo, Nb, Zr, Hf, Ta, W, Re, Os, Ir or Pt; n matches the formal oxidation state of the transition metal atom M; and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-­polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co­)oligomerization, polymerization and dimerization reactions.

  一种过渡金属配合物，为双芳胺吡啶MXn配合物，包括具有化学式(I)的双芳胺吡啶配体，其中R1-R5、R7-R9、R12和R14分别为独立的氢、可选择取代的烃基、惰性官能团，或R1-R3和R7-R9中的任意两个邻位取代基可以形成环，R6为氢、可选择取代的烃基、惰性官能团，或与R7或R4一起形成环，R10为氢、可选择取代的烃基、惰性官能团，或与R9或R4一起形成环，R11为氢、可选择取代的烃基、惰性官能团，或与R12或R5一起形成环，R15为氢、可选择取代的烃基、惰性官能团，或与R14或R5一起形成环，其中R13和至少一个R12和R14独立地选自可选择取代的C1-C30烷基、可选择取代的C4-C30烷氧基、卤素和可选择取代的C5-C20芳基，或R13与R12或R14一起形成环，或R12与R11一起形成环，R14与R15一起形成环，且至少一个R12、R13和R14为可选择取代的C4-C30烷氧基；M为过渡金属原子，特别选自Ti、V、Cr、Mn、Fe、Co、Ni、Pd、Rh、Ru、Mo、Nb、Zr、Hf、Ta、W、Re、Os、Ir或Pt；n与过渡金属原子M的形式氧化态相匹配；X为卤素、可选择取代的烃基、烷氧基、酰胺或氢化物。本发明的过渡金属配合物及其与非配位阴离子的复合物和含有此类配合物的催化系统在非极性介质和化学惰性非极性溶剂中具有良好的溶解性，特别是芳香烃类溶剂。该催化系统可用于广泛的(共)寡聚化、聚合和二聚化反应。
• TRANSITION METAL COMPLEXES
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP1740598A1

  公开（公告）日：2007-01-10
• US7547783B2
  申请人：——

  公开号：US7547783B2

  公开（公告）日：2009-06-16