prop-2-en-1-yl 2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1→4)-2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside | 1419710-96-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: prop-2-en-1-yl 2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1→4)-2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside
• CAS: 1419710-96-5
• 化学式: C₈₁H₉₀N₂O₂₇Si
• 分子量: 1551.69
• InChiKey: IVCURVOTGZJAQZ-NCASYQSESA-N

反应信息

• 作为反应物：
  描述：

  prop-2-en-1-yl 2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1→4)-2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 在 氟化氢吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 96.0h， 以46%的产率得到prop-2-en-1-yl 2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-2-deoxy-β-D-glucopyranosyl-(1→4)-2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-2-deoxy-α-D-glucopyranoside
  参考文献：
  名称：

  Synthesis of 13C-labeled and functionalized Hyaluronan derivatives for biophysical studies and surface modifications

  摘要：

  A convergent synthesis of a tetrasaccharide partial sequence of C-13-labeled Hyaluronan is presented. This tetrasaccharide can be used for biophysical studies as well as for surface modifications. Furthermore, tetrasaccharide 7 can be employed for the synthesis of additionally labeled higher oligomers of Hyaluronan on the basis of the presented methodology. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2012.11.025
• 作为产物：
  描述：

  、 乙酸酐 以 吡啶 为溶剂， 反应 16.0h， 以77.3 mg的产率得到prop-2-en-1-yl 2,3-di-O-benzoyl-4-O-[tert-butyl(dimethyl)silyl]-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1→4)-2,3-di-O-benzoyl-6-methyl-β-D-glucopyranuronosyl-(1→3)-2-(acetylamino)-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside
  参考文献：
  名称：

  Synthesis of 13C-labeled and functionalized Hyaluronan derivatives for biophysical studies and surface modifications

  摘要：

  A convergent synthesis of a tetrasaccharide partial sequence of C-13-labeled Hyaluronan is presented. This tetrasaccharide can be used for biophysical studies as well as for surface modifications. Furthermore, tetrasaccharide 7 can be employed for the synthesis of additionally labeled higher oligomers of Hyaluronan on the basis of the presented methodology. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2012.11.025