(2R,3R)-2,3-Dimethyl-oxirane-2-carboxylic acid (3aS,6R,10S,11R,11aS)-10-hydroxy-6,10-dimethyl-3-methylene-2,5-dioxo-dodecahydro-cyclodeca[b]furan-11-yl ester | 75196-27-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2R,3R)-2,3-Dimethyl-oxirane-2-carboxylic acid (3aS,6R,10S,11R,11aS)-10-hydroxy-6,10-dimethyl-3-methylene-2,5-dioxo-dodecahydro-cyclodeca[b]furan-11-yl ester
• CAS: 75196-27-9
• 化学式: C₂₀H₂₈O₇
• 分子量: 380.438
• InChiKey: XJAOGRKWGASQJV-AHLWSJCCSA-N

反应信息

• 作为反应物：
  描述：

  (2R,3R)-2,3-Dimethyl-oxirane-2-carboxylic acid (3aS,6R,10S,11R,11aS)-10-hydroxy-6,10-dimethyl-3-methylene-2,5-dioxo-dodecahydro-cyclodeca[b]furan-11-yl ester 在 氢溴酸 作用下， 以 甲醇 为溶剂， 反应 72.0h， 以30 mg的产率得到(2S,3R)-3-Bromo-2-hydroxy-2-methyl-butyric acid (3aS,6R,10S,11R,11aS)-10-hydroxy-6,10-dimethyl-3-methylene-2,5-dioxo-dodecahydro-cyclodeca[b]furan-11-yl ester
  参考文献：
  名称：

  Germacranolides of Inula eupatorioides. 2. Absolute configuration of the ineupatorolides

  摘要：

  DOI：

  10.1021/jo00340a029