(2E,4E)-2-((E)-(1S,6R,9R)-6-Hydroxy-9-hydroxymethyl-4-methyl-8-methylene-cyclonon-4-enyl)-6-methyl-hepta-2,4-diene-1,6-diol | 308276-90-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2E,4E)-2-((E)-(1S,6R,9R)-6-Hydroxy-9-hydroxymethyl-4-methyl-8-methylene-cyclonon-4-enyl)-6-methyl-hepta-2,4-diene-1,6-diol
• CAS: 308276-90-6
• 化学式: C₂₀H₃₂O₄
• 分子量: 336.472
• InChiKey: MZRKVFNZBLONLZ-NKUFAEKVSA-N

反应信息

• 作为反应物：
  描述：

  (2E,4E)-2-((E)-(1S,6R,9R)-6-Hydroxy-9-hydroxymethyl-4-methyl-8-methylene-cyclonon-4-enyl)-6-methyl-hepta-2,4-diene-1,6-diol 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 0.08h， 以82%的产率得到xeniaoxolane
  参考文献：
  名称：

  Xeniaoxolane: A New Xenicane-type Diterpenoid from the Okinawan Soft Coral, Xenia sp.; Absolute Configurations of Xeniaoxolane, Xeniolide-A and Xenialactol

  摘要：

  A new xenicane-type diterpenoid, xeniaoxolane, containing tetrahydrofuran, was isolated from the Okinawan soft coral of the genus, Xenia along with xeniolide-A and xenialactol. The relative configuration of xeniaoxolane was determined based on spectroscopic analysis. The absolute configuration of xeniolide-A was determined using the modified Mosher's method and those of xeniaoxolane and xenialactol, by chemical conversions. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)00689-x
• 作为产物：
  描述：

  xeniaoxolane 在 二异丁基氢化铝 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以33%的产率得到(2E,4E)-2-((E)-(1S,6R,9R)-6-Hydroxy-9-hydroxymethyl-4-methyl-8-methylene-cyclonon-4-enyl)-6-methyl-hepta-2,4-diene-1,6-diol
  参考文献：
  名称：

  Xeniaoxolane: A New Xenicane-type Diterpenoid from the Okinawan Soft Coral, Xenia sp.; Absolute Configurations of Xeniaoxolane, Xeniolide-A and Xenialactol

  摘要：

  A new xenicane-type diterpenoid, xeniaoxolane, containing tetrahydrofuran, was isolated from the Okinawan soft coral of the genus, Xenia along with xeniolide-A and xenialactol. The relative configuration of xeniaoxolane was determined based on spectroscopic analysis. The absolute configuration of xeniolide-A was determined using the modified Mosher's method and those of xeniaoxolane and xenialactol, by chemical conversions. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(00)00689-x