bis-(3-chloro-2,2-bis-chloromethyl-propyl) ether | 57690-45-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis-(3-chloro-2,2-bis-chloromethyl-propyl) ether
• 英文别名: Bis-(3-chlor-2,2-bis-chlormethyl-propyl)-aether；Dipentaerythrithexachlorhydrin；Hexachlor-dipentaerythrit；dipentaerythritol hexachloride；1,3-Dichloro-2-[[3-chloro-2,2-bis(chloromethyl)propoxy]methyl]-2-(chloromethyl)propane
• CAS: 57690-45-6
• 化学式: C₁₀H₁₆Cl₆O
• 分子量: 364.954
• InChiKey: KYYFSUDQIWMALK-UHFFFAOYSA-N

物化性质

• 熔点：
  139-141 °C(Solv: dichloromethane (75-09-2))
• 沸点：
  438.2±40.0 °C(Predicted)
• 密度：
  1.359±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis-(3-chloro-2,2-bis-chloromethyl-propyl) ether 、 二苯基膦 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 16.0h， 以69%的产率得到
  参考文献：
  名称：

  Helical Chirality Transmission through a p-Phenylene Fragment in a Hexa-λ⁵-phosphazene

  摘要：

  The helical chirality of a conformationally stable macrobicyclic tri-lambda(5)-phosphazene is propagated through to its C-3 symmetry axis and causes a measurable stereoinduction in the formation process of a second macrobicyclic tri-lambda(5)-phosphazene unit connected to the former one by a p-phenylene linker.

  DOI：

  10.1021/ol702183d
• 作为产物：
  描述：

  3,3-双(氯甲基)氧杂环丁烷 在 五氯化磷 作用下， 生成 bis-(3-chloro-2,2-bis-chloromethyl-propyl) ether
  参考文献：
  名称：

  Zhukova,T.I. et al., Journal of Organic Chemistry USSR (English Translation), 1975, vol. 11, p. 2018 - 2019

  摘要：

  DOI：

文献信息

• Process for producing chlorohydrins of polyhydric alcohols
  申请人：HEYDEN CHEMICAL CORP

  公开号：US02441595A1

  公开（公告）日：1948-05-18
• CONTROL OF SUSTAINED CASING PRESSURE IN WELLBORE ANNULI
  申请人：Albemarle Corporation

  公开号：EP3087155A1

  公开（公告）日：2016-11-02
• [EN] CONTROL OF SUSTAINED CASING PRESSURE IN WELLBORE ANNULI<br/>[FR] RÉGULATION DE PRESSION SOUTENUE SUR UN TUBAGE DANS DES ESPACES ANNULAIRES DE PUITS DE FORAGE
  申请人：ALBEMARLE CORP

  公开号：WO2015100004A1

  公开（公告）日：2015-07-02

  This invention provides a method for minimizing or relieving a sustained casing pressure in an annulus of a wellbore, where the annulus contains a first fluid having a density. The method comprises introducing a second fluid into the annulus. The second fluid has a density greater than the density of the first fluid and the second fluid is immiscible with the first fluid. The method is characterized in that the second fluid comprises at least one halogen-containing organic compound. The halogen-containing organic compound has one or more halogen atoms selected from fluorine, chlorine, bromine, and iodine, with the proviso that at least one of the halogen atoms is chlorine, bromine, or iodine.