2-iodoundecane | 152358-83-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 2-iodoundecane
• CAS: 152358-83-3
• 化学式: C₁₁H₂₃I
• 分子量: 282.208
• InChiKey: OMOUYWRNCDFZAM-UHFFFAOYSA-N

物化性质

• 沸点：
  278.2±8.0 °C(Predicted)
• 密度：
  1.230±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-iodoundecane 、 十一烷-2-硫醇 在 sodium hydroxide 作用下， 生成 bis-(1-methyl-decyl)-sulfane
  参考文献：
  名称：

  Schlenk,W., Justus Liebigs Annalen der Chemie, 1973, p. 1195 - 1209

  摘要：

  DOI：
• 作为产物：
  描述：

  2-iodododecane 生成 2-iodoundecane
  参考文献：
  名称：

  Kindel O., Herrmann F. J., Schmidt L., J. Radioanal. and Nucl. Chem. Art., 183 (1994) N 2, S 219-224

  摘要：

  DOI：

文献信息

• Functional transformation of aldehydes and ketones via homolytic induced decomposition of unsaturated peroxy acetals and peroxy ketals
  作者：L. Moutet、D. Bonafoux、M. Degueil-Castaing、B. Maillard

  DOI：10.1039/a808418a

  日期：——

  Induced decomposition of unsaturated peroxy acetals prepared from trimethyl orthoformate, dodecanal or 2-methylundecanal and 2,3-dimethyl-2-hydroperoxybut-3-ene, in the presence of ethyl iodoacetate, CCl4 or dodecanethiol, allowed respectively their iodo-, chloro- and hydro- decarbonylation with yields of over 70%; the same reaction applied to the monoperoxy ketal or diperoxy ketal of cyclohexanone in the presence of ethyl iodoacetate resulted in its functional transformation in methyl 6-iodohexanoate or 1,5-diiodopentane with respective yields of 65 and 40%.

  通过三甲基原甲酸酯、十二醛或2-甲基十一醛和2,3-二甲基-2-羟过氧丁-3-烯在乙基碘乙酸酯、CCl4或十二硫醇的存在下引发的未饱和过氧缩醛的分解反应，分别实现了它们的碘代、氯代和羟基脱羰反应，产率均超过70%；同样的反应在乙基碘乙酸酯存在下应用于环己酮的单过氧缩酮或双过氧缩酮，分别得到了甲基6-碘己酸酯或1,5-二碘戊烷，产率分别为65%和40%。
• Intramolecular Homolytic Displacements. 30. Functional Decarbonylative Transformations of Aldehydes via Homolytically Induced Decomposition of Unsaturated Peroxyacetals
  作者：Marie Degueil-Castaing、Laurent Moutet、Bernard Maillard

  DOI：10.1021/jo9918495

  日期：2000.6.1

  Homolytically induced decompositions of unsaturated peroxyacetals, synthesized from aldehydes, gave alkoxyalkoxyl radicals that yielded alkyl radicals by rapid beta-scission. The latter radicals could react with several types of "transfer agents" to smoothly bring about homolytic decarbonylative functional group transformations of aldehydes into halides, hydrocarbons, xanthates, alkanenitriles, 2-

  由醛合成的不饱和过氧缩醛的均相诱导分解产生了烷氧基烷氧基，该烷氧基通过快速的β断裂产生了烷基。后者可以与几种类型的“转移剂”发生反应，从而平稳地将醛类的均相脱羰基官能团转化为卤化物，烃，黄原酸酯，链烷腈，2-烷基-3-氯马来酸酐，1-苯基烷-1-炔，和2-烷基丙烯酸乙酯。
• Decarboxylative halogenation of aliphatic carboxylic acids catalyzed by iron salts under visible light
  作者：Jiahui Qian、Yu Zhang、Weining Zhao、Peng Hu

  DOI：10.1039/d3cc06149c

  日期：——

  In this article, we report a general protocol for the direct decarboxylative chlorination, iodination, and bromination of aliphatic carboxylic acids catalyzed by iron salts under visible light. This method enjoys a broad substrate scope with good functional group compatibility, including complex natural products. Benzylic and allylic C(sp3)–H bonds can be retained under the oxidative halogenation conditions

  在本文中，我们报告了可见光下铁盐催化脂肪族羧酸直接脱羧氯化、碘化和溴化的通用方案。该方法底物范围广泛，具有良好的官能团兼容性，包括复杂的天然产物。苯甲基和烯丙基C(sp 3 )–H键可以在氧化卤化条件下保留。该方法还显示出后期功能化的应用潜力。
• Compound, photocurable composition, cured product of same, printing ink, and printed matter curing the printing ink
  申请人：DIC Corporation

  公开号：US11079675B2

  公开（公告）日：2021-08-03

  A novel compound is used as a novel photopolymerization initiator, the novel compound having a molecular structure represented by general formula 1 below [R1 represents an alkyl group having 1 to 10 carbon atoms, R2 represents an alkyl group having 1 to 12 carbon atoms or the like, R3 represents an alkyl group having 1 to 12 carbon atoms or the like, R4 to R7 each independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or the like, Y1 represents an alkyl group having 3 to 19 carbon atoms or the like, Y2 represents an organic linking group, X1 represents an ethylene group or the like, X2 and X3 each represent an ethylene group or the like, Y3 represents a single bond or an alkylidene group, and n represents an integer of 1 to 3].

  一种新型化合物被用作新型光聚合引发剂，该新型化合物的分子结构如下通式 1 所示 [R1 代表具有 1 至 10 个碳原子的烷基，R2 代表具有 1 至 12 个碳原子的烷基或类似物，R3 代表具有 1 至 12 个碳原子的烷基或类似物，R4 至 R7 各自独立地代表氢原子、具有 1 至 8 个碳原子的烷基或类似物、Y1 代表具有 3 至 19 个碳原子的烷基或类似基团，Y2 代表有机连接基团，X1 代表乙烯基或类似基团，X2 和 X3 各自代表乙烯基或类似基团，Y3 代表单键或亚烷基，n 代表 1 至 3 的整数]。
• Houben; Boedler; Fischer, Chemische Berichte, 1936, vol. 69, p. 1782
  作者：Houben、Boedler、Fischer

  DOI：——

  日期：——