(2E,6Z,10E)-3,7,11-Trimethyl-14-(5-methyl-1-methylene-hex-4-enyl)-cyclotetradeca-2,6,10-trienone | 87538-24-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2E,6Z,10E)-3,7,11-Trimethyl-14-(5-methyl-1-methylene-hex-4-enyl)-cyclotetradeca-2,6,10-trienone
• CAS: 87538-24-7
• 化学式: C₂₅H₃₈O
• 分子量: 354.576
• InChiKey: PHMYRIHRKOWHDJ-XYBLUVTKSA-N

反应信息

• 作为反应物：
  描述：

  (2E,6Z,10E)-3,7,11-Trimethyl-14-(5-methyl-1-methylene-hex-4-enyl)-cyclotetradeca-2,6,10-trienone 在 吡啶 、 aluminium hydride 作用下， 生成 Acetic acid (2E,6Z,10E)-3,7,11-trimethyl-14-(5-methyl-1-methylene-hex-4-enyl)-cyclotetradeca-2,6,10-trienyl ester
  参考文献：
  名称：

  SYNTHESIS OFdl-(2E,6Z,10E)-CERICERENE FOR ELUCIDATION OF THE PROPOSED STRUCTURE OF CERICEROL-I

  摘要：

  dl-(2E,6Z,10E)-Cericerene was synthesized and its spectral data were compared with those of cericerene derived from cericerol-I, revealing that the reported arrangement of annular double bonds of cericerol-I and related compounds should be revised.

  DOI：

  10.1246/cl.1983.1073
• 作为产物：
  描述：

  (2E,6Z,10E)-geranylfarnesic acid 在 氯化亚砜 、 四氯化锡 、 lithium bromide 作用下， 以 吡啶 为溶剂， 反应 7.0h， 生成 (2E,6Z,10E)-3,7,11-Trimethyl-14-(5-methyl-1-methylene-hex-4-enyl)-cyclotetradeca-2,6,10-trienone
  参考文献：
  名称：

  SYNTHESIS OFdl-(2E,6Z,10E)-CERICERENE FOR ELUCIDATION OF THE PROPOSED STRUCTURE OF CERICEROL-I

  摘要：

  dl-(2E,6Z,10E)-Cericerene was synthesized and its spectral data were compared with those of cericerene derived from cericerol-I, revealing that the reported arrangement of annular double bonds of cericerol-I and related compounds should be revised.

  DOI：

  10.1246/cl.1983.1073