[(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl] prop-2-enoate | 128638-93-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: [(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl] prop-2-enoate
• CAS: 128638-93-7
• 化学式: C₁₈H₂₈O₂
• 分子量: 276.419
• InChiKey: CGFDWSBCBFWGIV-IUBLYSDUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl] prop-2-enoate 在 三乙基硅烷 、 Wilkinson's catalyst 作用下， 以 苯 为溶剂， 反应 40.0h， 以75%的产率得到2,6,10-trimethyl-2,6,10-dodecatriene
  参考文献：
  名称：

  Liu, Hsing-Jang; Zhu, Bing-Yan, Synthetic Communications, 1990, vol. 20, # 4, p. 557 - 562

  摘要：

  DOI：

文献信息

• ADHESIVES COMPRISING CROSSLINKER WITH (METH)ACRYLATE GROUP AND OLEFIN GROUP AND METHODS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20150037526A1

  公开（公告）日：2015-02-05

  There is provided an article having a release liner and a pressure sensitive adhesive composition disposed along a major surface of the release liner, where the pressure sensitive adhesive composition has at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C 6 -C 20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl(meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C 6 -C 20 olefin group, the olefin group being optionally substituted.

  提供了一种具有放置脱离层和压敏粘合剂组成物的文章，其中压敏粘合剂组成物在脱离层的一个主要表面上具有至少50重量％的来自烷基甲基（丙烯酸酯）单体的聚合单元;以及0.2至15重量％的至少一种交联单体，包括一个（甲）丙烯酸酯基团和一个C6-C20烯烃基团，烯烃基团可选择性地被取代。在另一种实施方式中，描述了一种粘合剂组成物，其中包括糖浆，其中i）自由基聚合性溶剂单体;和ii）溶质（甲）丙烯酸聚合物，其中包括来自一个或多个烷基（甲）丙烯酸酯单体的聚合单元;其中糖浆包含至少一种交联单体或（甲）丙烯酸溶质聚合物包含来自至少一种交联单体的聚合单元，所述交联单体包括一个（甲）丙烯酸酯基团和一个C6-C20烯烃基团，烯烃基团可选择性地被取代。
• US9475967B2
  申请人：——

  公开号：US9475967B2

  公开（公告）日：2016-10-25
• [EN] ADHESIVES COMPRISING CROSSLINKER WITH (METH)ACRYLATE GROUP AND OLEFIN GROUP AND METHODS<br/>[FR] ADHÉSIFS COMPRENANT UN AGENT DE RÉTICULATION COMPORTANT UN GROUPE (MÉTH)ACRYLATE ET UN GROUPE OLÉFINIQUE, ET PROCÉDÉS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2014172185A1

  公开（公告）日：2014-10-23

  A pressure sensitive adhesive composition is described comprising at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In yet other embodiments, methods of preparing adhesive compositions are described
• Liu, Hsing-Jang; Zhu, Bing-Yan, Synthetic Communications, 1990, vol. 20, # 4, p. 557 - 562
  作者：Liu, Hsing-Jang、Zhu, Bing-Yan

  DOI：——

  日期：——