2-[(E)-3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acryloyl]-succinic acid dimethyl ester | 86787-18-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-[(E)-3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acryloyl]-succinic acid dimethyl ester
• CAS: 86787-18-0
• 化学式: C₁₈H₂₆O₅
• 分子量: 322.401
• InChiKey: BUIFCIJXAOOZNX-CMDGGOBGSA-N

反应信息

• 作为反应物：
  描述：

  2-[(E)-3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acryloyl]-succinic acid dimethyl ester 以 甲醇 为溶剂， 生成 2-(5,5,8a-Trimethyl-6,7,8,8a-tetrahydro-5H-chromen-2-yl)-succinic acid dimethyl ester
  参考文献：
  名称：

  PHOTOCHEMISTRY OF 10-ALKYL-10-CARBOMETHOXY-β-IONONE UNDER BASIC CONDITIONS

  摘要：

  Irradiation of 10-alkyl-10-carbomethoxy-β-ionones 1a, b under basic conditions gave 2-oxatricyclo[4,4,0,01.5]-decane derivatives 5a, b; the mechanism involves initial cis–trans isomerization of the C7–C8 double bonds followed by [2+4] cycloaddition reaction and double bonds isomerization.

  DOI：

  10.1246/cl.1983.651