4-(羟甲基)-6,6-二甲基二环[3.1.1]庚烷-4-醇 | 2005-76-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 4-(羟甲基)-6,6-二甲基二环[3.1.1]庚烷-4-醇
• 英文名称: pinane-2α,10-diol
• 英文别名: Nopinenglycol；pinanediol-(2.10)；Pinandiol-(2.10)；Nopinenglykol；6.6-Dimethyl-2-oxymethyl-bicyclo-[1.1.3]-heptanol-(2)；6.6-Dimethyl-2-methylol-bicyclo-[1.1.3]-heptanol-(2)；β-Pinenglykol；Pinan-2,10-diol；2-(Hydroxymethyl)-6,6-dimethylbicyclo[3.1.1]heptan-2-ol
• CAS: 2005-76-7
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: VXXAKGMRLUXFQH-UHFFFAOYSA-N

物化性质

• 熔点：
  80-82 °C
• 沸点：
  147-149 °C(Press: 2 Torr)
• 密度：
  1.080±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2906199090

反应信息

• 作为反应物：
  描述：

  4-(羟甲基)-6,6-二甲基二环[3.1.1]庚烷-4-醇 、 furan-2,3,5(4H)-trione pyridine (1:1) 、 alkaline earth salt of/the/ methylsulfuric acid 生成 nopinic acid
  参考文献：
  名称：

  Wallach, Justus Liebigs Annalen der Chemie, 1909, vol. 368, p. 15

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium permanganate 作用下， 生成 4-(羟甲基)-6,6-二甲基二环[3.1.1]庚烷-4-醇
  参考文献：
  名称：

  Wallach, Justus Liebigs Annalen der Chemie, 1908, vol. 363, p. 11

  摘要：

  DOI：

文献信息

• Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods for the Preparation of 1,2-Diols, Aldehydes, and Ketones
  作者：Azhong Wang、Huanfeng Jiang

  DOI：10.1021/jo100125q

  日期：2010.4.2

  1,2-Diols, aldehydes, and ketones are important intermediates in chemical synthesis, and alkenes are possible precursors for 1,2-diols, aldehydes, and ketones. Herein, novel and environmentally benign methods for palladium-catalyzed dihydroxylation and oxidative cleavage of olefins with oxygen as sole oxidant are presented. The cleavage reactions were performed with acid as additive in aqueous solution

  1,2-二醇，醛和酮是化学合成中的重要中间体，烯烃是1,2-二醇，醛和酮的可能前体。在此，提出了新颖的且环境友好的方法，该方法用于钯催化的二羟基化作用以及用氧作为唯一氧化剂的烯烃的氧化裂解。裂解反应是用酸作为添加剂在水溶液中进行的，而1,2-二醇是在碱的存在下形成的。已经证明广泛的底物范围允许单取代的芳族和脂族末端烯烃，1，2-二取代的和1，1-二取代的烯烃。二氧-Pd II配合物的裂解反应意味着1,2-二醇可能是烯烃裂解的关键中间体。
• Catalytic Hydroxylation of Olefins by Polymer-Bound Osmium Tetroxide
  作者：Gianfranco Cainelli、Michele Contento、Francesco Manescalchi、Laura Plessi

  DOI：10.1055/s-1989-27145

  日期：——

  Osmium tetroxide, linked to insoluble crosslinked polymers and copolymers bearing tertiary amino functions, has been used in the presence of secondary oxidants, such as hydrogen peroxide, tert-butyl hydroperoxide and trimethylamine N-oxide, to accomplish the catalytic hydroxylation of olefins. The polymeric reagent offers the advantages of easy and safe handling, and simple separation from the reaction medium. Generally good yields of vicinal diols have been obtained.

  四氧化锇与具有三级氨基功能的不可溶交联聚合物和共聚物相结合，在次级氧化剂（如过氧化氢、叔丁基过氧化氢和N-氧化三甲基胺）的 presence 中被用于催化烯烃的羟基化。聚合物试剂提供了易于安全操作和简单从反应介质中分离的优点。通常获得了较好的邻二醇产率。
• Dye and ink jet printing ink
  申请人：KONICA MINOLTA HOLDINGS, INC.

  公开号：US20040106782A1

  公开（公告）日：2004-06-03

  A dye is disclosed, which is represented by the following formula: 1 wherein Z is an atomic group necessary to form a 6-membered nitrogen containing aromatic ring; R 11 is a hydrogen bonding group; R 12 , R 13 and R 14 are independently a hydrogen atom or a substituent; n11 and n13 are each an integer of 1 to 4; n12 is an integer of 1 to 3. There is also disclosed an ink for ink jet printing which contains the foregoing dye.

  揭示了一种染料，其表示为以下公式：1其中Z是形成一个含氮6元环芳香环所必需的原子基团；R11是一个氢键结合基团；R12、R13和R14分别是氢原子或取代基；n11和n13各自是1至4的整数；n12是1至3的整数。还披露了一种喷墨打印墨水，其中包含上述染料。
• Thermal transfer recording material and thermal transfer recording method
  申请人：KONICA CORPORATION

  公开号：EP1231072A2

  公开（公告）日：2002-08-14

  A thermal transfer recording material comprising a support having thereon an image transferring layer containing a coloring material represented by Formula (I), wherein each R11 and R12 is independently a substituted or unsubstituted aliphatic group; R13 is a substituent and n is an integer of 0 to 4, provided that when n is 2 or more, a plurality of R13s are the same or different; R14 is an alkyl group; and each R15 and R16 is independently an alkyl group having 3 to 8 carbon atoms.

  一种热转印记录材料，包括一个支撑体，支撑体上有一个含有由式（I）表示的着色材料的图像转移层、 其中每个 R11 和 R12 独立地为取代或未取代的脂肪族基团；R13 为取代基，n 为 0 至 4 的整数，但当 n 为 2 或更多时，多个 R13 相同或不同；R14 为烷基；每个 R15 和 R16 独立地为具有 3 至 8 个碳原子的烷基。
• DECOLORING INK FOR INK JET PRINGING AND INK JET PRINTING METHOD USING IT
  申请人：Ajinomoto Co., Inc.

  公开号：EP1391486A1

  公开（公告）日：2004-02-25

  An inclusion of an ang-khak pigment enables printed characters and/or images to be preserved as long as they are kept in the dark, but they are quickly decolored on exposure to visible light and/or ultraviolet light when they are no longer needed.

  加入ang-khak颜料后，印刷的字符和/或图像只要保存在黑暗中就能保存下来，但当不再需要它们时，暴露在可见光和/或紫外线下就会迅速脱色。