3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-Pentadecafluoro-1,12-diiodo-10-trifluoromethyl-dodecane | 1027379-92-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-Pentadecafluoro-1,12-diiodo-10-trifluoromethyl-dodecane
• 英文别名: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-pentadecafluoro-1,12-diiodo-10-(trifluoromethyl)dodecane
• CAS: 1027379-92-5
• 化学式: C₁₃H₈F₁₈I₂
• 分子量: 759.987
• InChiKey: JNQXRXWJRPEMJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  33
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-Pentadecafluoro-1,12-diiodo-10-trifluoromethyl-dodecane 在 硫酸 、 水 作用下， 生成 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-Pentadecafluoro-10-trifluoromethyl-dodecane-1,12-diol
  参考文献：
  名称：

  Difunctional Monomers Based on Perfluoropropylene Telomers

  摘要：

  Telomers of perfluoropropylene with alpha,omega-diiodoperfluoroalkanes were converted to branched-chain difunctional condensation monomers. The reaction of ethylene with the telomers gave alpha,omega-bis(iodoethyl)perfluoroalkanes, which were converted to the corresponding diols by reaction with fuming sulfuric acid. The reaction of the branched-chain alpha,omega-bis(iodoethyl)perfluoroalkane a with sodium azide gave the corresponding alpha,omega-bis(azidoethyl)perfluoroalkanes. Hydrogenation of the alpha,omega-bis(azidoethyl)perfluoroalkanes gave diamines. Phosgenation of the amino groups gave diisocyanates.

  DOI：

  10.1021/jo00101a048
• 作为产物：
  描述：

  乙烯 、 1,8-Diiodoperfluorononane 160.0 ℃ 、2.07 MPa 条件下， 以88%的产率得到3,3,4,4,5,5,6,6,7,7,8,8,9,9,10-Pentadecafluoro-1,12-diiodo-10-trifluoromethyl-dodecane
  参考文献：
  名称：

  Difunctional Monomers Based on Perfluoropropylene Telomers

  摘要：

  Telomers of perfluoropropylene with alpha,omega-diiodoperfluoroalkanes were converted to branched-chain difunctional condensation monomers. The reaction of ethylene with the telomers gave alpha,omega-bis(iodoethyl)perfluoroalkanes, which were converted to the corresponding diols by reaction with fuming sulfuric acid. The reaction of the branched-chain alpha,omega-bis(iodoethyl)perfluoroalkane a with sodium azide gave the corresponding alpha,omega-bis(azidoethyl)perfluoroalkanes. Hydrogenation of the alpha,omega-bis(azidoethyl)perfluoroalkanes gave diamines. Phosgenation of the amino groups gave diisocyanates.

  DOI：

  10.1021/jo00101a048

文献信息

• US6084057A
  申请人：——

  公开号：US6084057A

  公开（公告）日：2000-07-04
• US6451960B1
  申请人：——

  公开号：US6451960B1

  公开（公告）日：2002-09-17
• US6552161B1
  申请人：——

  公开号：US6552161B1

  公开（公告）日：2003-04-22