Acetic acid (E)-(1S,3R,6S,10S,14R,16R)-6-acetoxy-14,16-dihydroxy-5,5,9,14-tetramethyl-4-oxo-tricyclo[11.2.1.0^1,10]hexadec-8-en-3-yl ester | 96829-65-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Acetic acid (E)-(1S,3R,6S,10S,14R,16R)-6-acetoxy-14,16-dihydroxy-5,5,9,14-tetramethyl-4-oxo-tricyclo[11.2.1.0^1,10]hexadec-8-en-3-yl ester
• CAS: 96829-65-1
• 化学式: C₂₄H₃₆O₇
• 分子量: 436.546
• InChiKey: XARRSOHEHITTRS-RQPLBWLNSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (E)-(1S,3R,6S,10S,14R,16R)-6-acetoxy-14,16-dihydroxy-5,5,9,14-tetramethyl-4-oxo-tricyclo[11.2.1.0^1,10]hexadec-8-en-3-yl ester 以 氘代氯仿 为溶剂， 生成 Grayanatoxin-II-3,6-diacetat
  参考文献：
  名称：

  A NEW DITERPENOID FROMLEUCOTHOE GRAYANAMAX.

  摘要：

  A new minor diterpenoid was isolated from the leaves of Leucothoe grayana Max., and its structure was characterized as a secograyanane derivative(1, 3(S), 6(R), 14(R), 16(R)-tetrahydroxy-5-oxo-5,10-seco-ent-kaur-1(10)-ene) by spectroscopic and chemical studies.

  DOI：

  10.1246/cl.1985.443
• 作为产物：
  描述：

  乙酸酐 、 3(S),6(R),14(R),16(R)-tetrahydroxy-5-oxo-5,10-seco-ent-kaur-1(10)-ene 在 氘代吡啶 作用下， 生成 Grayanatoxin-II-3,6-diacetat 、 Acetic acid (E)-(1S,3R,6S,10S,14R,16R)-6-acetoxy-14,16-dihydroxy-5,5,9,14-tetramethyl-4-oxo-tricyclo[11.2.1.0^1,10]hexadec-8-en-3-yl ester
  参考文献：
  名称：

  A NEW DITERPENOID FROMLEUCOTHOE GRAYANAMAX.

  摘要：

  A new minor diterpenoid was isolated from the leaves of Leucothoe grayana Max., and its structure was characterized as a secograyanane derivative(1, 3(S), 6(R), 14(R), 16(R)-tetrahydroxy-5-oxo-5,10-seco-ent-kaur-1(10)-ene) by spectroscopic and chemical studies.

  DOI：

  10.1246/cl.1985.443