7-iodo-9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline | 1259289-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-iodo-9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline
• CAS: 1259289-45-6
• 化学式: C₁₈H₁₄IN
• 分子量: 371.22
• InChiKey: XYMSCFNIDJPEJJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  环戊酮 、 2-氨基二苯甲酮 在 N,N,N-trimethylbenzenemethanaminium dichloroiodate 、 溶剂黄146 、 zinc(II) chloride 作用下， 反应 10.0h， 以75%的产率得到7-iodo-9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline
  参考文献：
  名称：

  One-Pot Three-Component Synthesis of 6-Bromoquinolines and 6-Iodoquinolines

  摘要：

  AbstractThree‐component one‐pot synthesis of some novel 6‐bromoquinolines 5a‐5h involving the treatment of 2‐aminobenzophenone, α‐methylene carbonyl compounds, and tetrabutyl‐ammonium tribromide was achieved, and this reaction was extended to the preparation of 6‐iodoquinolines 6a‐6e by a three‐component reaction 2‐aminobenzophenone, α‐methylene carbonyl compounds, and benzyltrimethylammonium dichloroiodate in the presence of ZnCl2.

  DOI：

  10.1002/jccs.201000086