5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexafluorocalix[6]arene | 1263217-57-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexafluorocalix[6]arene
• CAS: 1263217-57-7
• 化学式: C₇₂H₉₀F₆O₆
• 分子量: 1165.49
• InChiKey: PSWIIXYCKGVBTO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  5,11,17,23,29,35-hexa-tert-butyl-2,8,14,20,26,32-hexahydroxy-37,38,39,40,41,42-hexamethoxycalix[6]arene 在 二乙胺基三氟化硫 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以19%的产率得到5,11,17,23,29,35-hexa(tert-butyl)-37,38,39,40,41,42-hexamethoxy-2,8,14,20,26,32-hexafluorocalix[6]arene
  参考文献：
  名称：

  Calix[6]arenes incorporating functionalised substituents at the methylene bridges

  摘要：

  The hexabromocalix[6]arene 5 reacts with p-tert-Bu-phenol, thymol and propargyl alcohol to afford the corresponding hexasubstituted methylene-functionalised calixarenes. The substituents at the bridges were further functionalised via acetylation or click chemistry. Reaction of the hexahydroxy derivative 10 with DAST afforded 11, a first example of a calixarene with all bridges monofluorinated.

  DOI：

  10.1080/10610278.2010.500728