(R)-N-(2-hydroxy-3,5-dibromobenzyl){(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide | 1416721-11-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (R)-N-(2-hydroxy-3,5-dibromobenzyl){(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide
• CAS: 1416721-11-3
• 化学式: C₁₇H₂₃Br₂NO₂S
• 分子量: 465.249
• InChiKey: SCTXOYBPMRWYSK-JJPRQUPASA-N

反应信息

• 作为产物：
  描述：

  (R,S)-N-(E)-(2-hydroxy-3,5-dibromobenzylidene){(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]-heptane}-2-sulfinamide 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以14%的产率得到(S)-N-(2-hydroxy-3,5-dibromobenzyl){(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane}-2-sulfinamide
  参考文献：
  名称：

  Synthesis and reduction of new sulfinimines with isobornane structure

  摘要：

  Synthesis of sulfenimines proceeding from isobornanethiol with yields up to 78% was performed. They were oxidized to diastereomeric isobornylsulfinimines and the latter were reduced to N-substituted isobornylsulfinamides in high yields.

  DOI：

  10.1134/s1070428012110024