Dihydrochloride Salt of N-(4-(4'-guanidinophenyl)phenylamine)-4-aminopentanamide | 2050-31-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: Dihydrochloride Salt of N-(4-(4'-guanidinophenyl)phenylamine)-4-aminopentanamide
• 英文别名: 3-methylcyclohexa-1,4-diene；1,4-dihydrotoluene；3-Methyl-cyclohexa-1,4-dien；1-Methyl-cyclohexadien-2,5；1,4-Dihydro-toluol；1,4-Dihydrotoluol；1,4-Cyclohexadiene, 6-methyl
• CAS: 2050-31-9
• 化学式: C₇H₁₀
• 分子量: 94.1564
• InChiKey: LDXWTNBYKFXMDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Dihydrochloride Salt of N-(4-(4'-guanidinophenyl)phenylamine)-4-aminopentanamide 在 potassium tert-butylate 作用下， 以 二甲基亚砜 、 正戊烷 为溶剂， 反应 16.5h， 生成 2-methyl-1H-cyclopropabenzene
  参考文献：
  名称：

  Regioselective ring opening in substituted benzocyclopropenes. An alternative or complementary mechanism for electrophilic substitution involving attack at .alpha. bond

  摘要：

  DOI：

  10.1021/ja00543a032
• 作为产物：
  描述：

  toluene-4-sulfonic acid cyclohexa-2,5-dienylmethyl ester 在 lithium aluminium tetrahydride 作用下， 生成 Dihydrochloride Salt of N-(4-(4'-guanidinophenyl)phenylamine)-4-aminopentanamide
  参考文献：
  名称：

  Regioselective ring opening in substituted benzocyclopropenes. An alternative or complementary mechanism for electrophilic substitution involving attack at .alpha. bond

  摘要：

  DOI：

  10.1021/ja00543a032

文献信息

• Sequential synthesis of some tetraosmium–arene clusters
  作者：Brian F. G. Johnson、Alexander J. Blake、Caroline M. Martin、Dario Braga、Emilio Parisini、Hong Chen

  DOI：10.1039/dt9940002167

  日期：——

  On activation with Me3NO the tetrahydrido-tetranuclear cluster [Os4(mu-H)4(CO)12] 1 underwent reaction with cyclohexa-1,3-diene in CH2Cl2 under ambient conditions to give, as the major products, the four organometallic clusters [Os4(mu-H)3(CO)11(eta3-C6H9)] 2, [Os4(mu-H)2(CO)12(eta2-C6H8)] 3, [Os4(mu-H)2(CO)11(eta4-C6H8)] 4 and [Os4(mu-H)2(CO)10(eta6-C6H6)] 5. On heating in hexane, 3 is converted into 4 and subsequently 4 into 5. Compound 5 underwent further reaction with Me3NO in CH2Cl2 in the presence of cyclohexa-1,3-diene to produce [Os4(CO)9(eta6-C6H6)(eta4-C6H8)] 6 and [Os4(mu-H)2(CO)8(eta6-C6H6)(eta4-C6H8)] 7. Structural analyses of 4 and 7 by single-crystal X-ray diffraction have shown that the C6H8 ligand is bonded through two alkene bonds and that the benzene ligand in 7 is co-ordinated in an eta6 fashion. In each case the ligands are bonded to single osmium atoms only. Compound 5 was also found to react with Me3NO in CH2Cl2 in the presence of benzene yielding [Os4(CO)8(eta6-C6H6)2] 8, whilst with either toluene or mesitylene it undergoes arene displacement to produce [Os4(mu-H)2(CO)10(eta6-C6H5Me)] 9 or [Os4(mu-H)2(CO)10(eta6-C6H4Me2-1,3)] 10 respectively.
• AZZENA, UGO;COSSU, SERGIO;DE, LUCCHI OTTORINO;MELLONI, GIOVANNI, TETRAHEDRON LETT., 30,(1989) N4, C. 1845-1848
  作者：AZZENA, UGO、COSSU, SERGIO、DE, LUCCHI OTTORINO、MELLONI, GIOVANNI

  DOI：——

  日期：——
• Nojima Kazuhiro, Isogami Chiho, Hirobe Masaaki, Chem. and Pharm. Bull, 41 (1993) N 12, S 2106-2108
  作者：Nojima Kazuhiro, Isogami Chiho, Hirobe Masaaki

  DOI：——

  日期：——
• Regioselective ring opening in substituted benzocyclopropenes. An alternative or complementary mechanism for electrophilic substitution involving attack at .alpha. bond
  作者：Lim Keow Bee、Peter J. Garratt、Muzamil M. Mansuri

  DOI：10.1021/ja00543a032

  日期：1980.11