3-hexadecyl-pentane-2,4-dione | 73923-17-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-hexadecyl-pentane-2,4-dione
• 英文别名: 3-Hexadecylpentane-2,4-dione；3-hexadecylpentane-2,4-dione
• CAS: 73923-17-8
• 化学式: C₂₁H₄₀O₂
• 分子量: 324.547
• InChiKey: ROYPXXFQXOLMCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  23
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  sodium (Z)-4-oxopent-2-en-2-olate 、 溴代十六烷 以 二甲基亚砜 为溶剂， 以71%的产率得到3-hexadecyl-pentane-2,4-dione
  参考文献：
  名称：

  Oligomerization and isomerization of olefins by catalysts derived from nickel complexes of dithio-β-diketonates

  摘要：

  The complexes [Ni{R1C(S)CR2C(S)R3}2] 1 and [Ni(R1C(S)CR2C(S)R3}(PL1L2L3)X] 2 (R, L = alkyl, aryl or CF3; X = Cl, Br or 1) have been prepared. The complexes 2 can be chemically anchored to polystyrene or silica-alumina supports via pendant phosphine ligands to form the derivatives 3. The species 2 and 3 in combination with a suitable co-catalyst form extremely active catalysts for the oligomerization of ethylene, propylene or butenes. The immobilised systems show no significant signs of leaching after 24 h operation. In general the oligomerization is highly selective to dimers, however, selectivity and catalyst activity are markedly affected by changes in L. Changes in R affect catalyst activity only.

  DOI：

  10.1039/dt9930000059

文献信息

• Kerr, James M.; Suckling, Colin J.; Bamfield, Peter, Journal of the Chemical Society. Perkin transactions I, 1990, # 4, p. 887 - 895
  作者：Kerr, James M.、Suckling, Colin J.、Bamfield, Peter

  DOI：——

  日期：——
• A PERCHLORATE SOLUTION IMPROVED IN SAFETY, AND A METHOD FOR HEAT-STABILIZING CHLORINE-CONTAINING RESIN COMPOSITIONS
  申请人：Akishima Chemical Industries Co., Ltd.

  公开号：EP2429940A1

  公开（公告）日：2012-03-21
• PERCHLORATE SOLUTION IMPROVED IN SAFETY, AND A METHOD FOR HEAT-STABILIZING CHLORINE-CONTAINING RESIN COMPOSITIONS
  申请人：Yoshino Kenji

  公开号：US20120123038A1

  公开（公告）日：2012-05-17

  To improve the handlability and safety of a perchlorate solution used as a stabilizer for chlorine-containing resins. This invention provides a perchlorate solution of improved handlability and safety and a method for heat-stabilizing chlorine-containing resin compositions by adding (a) 0.004 to 10 parts by weight of a perchlorate solution containing 1 to 60% by weight of perchlorate, 5 to 50% by weight of water-soluble organic solvent and 20 to 94% by weight of water, and (b) 0.001 to 10 parts by weight of at least one silicate compound represented by the general formula (I) to 100 parts by weight of a chlorine-containing resin: M(O)a nSiO 2 mH 2 O   (I) in which M is at least one metal selected from alkaline earth metals and aluminum, a is 1 when M is an alkaline earth metal and 3/2 where M is aluminum, n is from 1 to 5, and m is any positive integer.
• US4252698A
  申请人：——

  公开号：US4252698A

  公开（公告）日：1981-02-24
• [EN] A PERCHLORATE SOLUTION IMPROVED IN SAFETY, AND A METHOD FOR HEAT-STABILIZING CHLORINE-CONTAINING RESIN COMPOSITIONS<br/>[FR] SOLUTION DE PERCHLORATE AMÉLIORÉE EN TERMES DE SÉCURITÉ ET PROCÉDÉ POUR LA STABILISATION VIS-À-VIS DE LA CHALEUR DE COMPOSITIONS DE RÉSINE CONTENANT DU CHLORE
  申请人：AKISHIMA KAGAKU KOGYO

  公开号：WO2010131782A1

  公开（公告）日：2010-11-18

  To improve the handlability and safety of a perchlorate solution used as a stabilizer for chlorine-containing resins. This invention provides a perchlorate solution of improved handlablity and safety and a method for heat-stabilizing chlorine-containing resin compositions by adding (a) 0.004 to 10 parts by weight of a perchlorate solution containing 1 to 60 % by weight of perchlorate, 5 to 50 % by weight of water-soluble organic solvent and 20 to 94 % by weight of water, and (b) 0.001 to 10 parts by weight of at least one silicate compound represented by the general formula (I) to 100 parts by weight of a chlorine-containing resin: M(O)a nSiO2mH2O (I) in which M is at least one metal selected from alkaline earth metals and aluminum, a is 1 when M is an alkaline earth metal and 3/2 where M is aluminum, n is from 1 to 5, and m is any positive integer.