2-Methacryloyloxy-5,6-epoxy-bicyclo<2.2.1>heptan | 86311-28-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-Methacryloyloxy-5,6-epoxy-bicyclo<2.2.1>heptan
• 英文别名: 3-Oxatricyclo[3.2.1.02,4]octan-6-yl 2-methylprop-2-enoate
• CAS: 86311-28-6
• 化学式: C₁₁H₁₄O₃
• 分子量: 194.23
• InChiKey: LHAKXESMFXXNMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5-降冰片烯-2-醇甲基丙烯酸酯 、 双氧水 以97%的产率得到
  参考文献：
  名称：

  TESHIGAHARA, SATOSHI;KANO, YOSHIAKI, TOSO KEHNKYU XOKOKU, 35,(1991) N, S. 47-56

  摘要：

  DOI：

文献信息

• (Meth) acrylate derivative, polymer and photoresist composition having lactone structure, and method for forming pattern by using it
  申请人：——

  公开号：US20010026901A1

  公开（公告）日：2001-10-04

  There are here disclosed a photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: 1 wherein R 1 , R 2 , R 3 and R 5 are each a hydrogen atom or a methyl group; R 4 is an acid-labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has an acid labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group, or a hydrocarbon group having 3 to 13 carbon atoms, which has an epoxy group; R 6 is a hydrogen atom, a hydrocarbon group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group; x, y and z are optional values which meet x+y+z=1, 0

  本发明公开了一种用于使用220纳米或更短波长的光进行光刻的光阻材料，其包括至少一种由以下式（2）表示的聚合物和用于通过曝光产���酸的光酸发生剂： 其中，R1、R2、R3和R5分别为氢原子或甲基基团；R4为酸可裂解基团、具有7至13个碳原子的脂环烃基团，其具有酸可裂解基团、具有7至13个碳原子的脂环烃基团，其具有羧基，或具有3至13个碳原子的烃基团，其具有环氧基团；R6为氢原子、具有1至12个碳原子的烃基团，或具有7至13个碳原子的脂环烃基团，其具有羧基；x、y和z是可选的值，满足x+y+z=1，0≤x≤1，0≤y<1和0≤z<1；聚合物的重均分子量在2000至200000范围内，以及具有由式（3）表示的脂环内酯结构的（甲）丙烯酸酯单元的树脂： 其中，R8为氢原子或甲基基团，R9为具有脂环内酯结构的7至16个碳原子的烃基团。
• (Meth)acrylate derivative, polymer and photoresist composition having lactone structure, and method for forming pattern by using it
  申请人：Maeda Katsumi

  公开号：US20070218403A1

  公开（公告）日：2007-09-20

  There are here disclosed a photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: wherein R 1 , R 2 , R 3 and R 5 are each a hydrogen atom or a methyl group; R 4 is an acid-labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has an acid labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group, or a hydrocarbon group having 3 to 13 carbon atoms, which has an epoxy group; R 6 is a hydrogen atom, a hydrocarbon group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group; x, y and z are optional values which meet x+y+z=1, 0

  本文披露了一种光刻用220纳米或以下光的光阻材料，包括至少一种由以下式子（2）表示的聚合物和用于曝光生成酸的光酸发生剂： 其中，R1、R2、R3和R5分别是氢原子或甲基基团；R4是酸敏感基团、具有7至13个碳原子的脂环烃基团、具有酸敏感基团的7至13个碳原子的脂环烃基团、具有3至13个碳原子的环烃基团、具有环氧基团；R6是氢原子、具有1至12个碳原子的碳氢基团或具有7至13个碳原子的脂环烃基团，具有羧基；x、y和z是可选值，满足x+y+z=1，0树脂： 其中，R8是氢原子或甲基基团，R9是具有脂环内酯结构的7至16个碳原子的碳氢基团。
• (METH)ACRYLATE DERIVATIVE, POLYMER AND PHOTORESIST COMPOSITION HAVING LACTONE STRUCTURE, AND METHOD FOR FORMING PATTERN BY USING IT
  申请人：Maeda Katsumi

  公开号：US20110196122A1

  公开（公告）日：2011-08-11

  There are here disclosed a photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: wherein R 1 , R 2 , R 3 and R 5 are each a hydrogen atom or a methyl group; R 4 is an acid-labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has an acid labile group, an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group, or a hydrocarbon group having 3 to 13 carbon atoms, which has an epoxy group; R 6 is a hydrogen atom, a hydrocarbon group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 7 to 13 carbon atoms, which has a carboxyl group; x, y and z are optional values which meet x+y+z=1, 0

  本文披露了一种光刻用于220nm或更低波长的光的光阻材料，其包括至少由以下化学式(2)表示的聚合物和用于曝光后生成酸的光酸发生剂：其中，R1、R2、R3和R5分别为氢原子或甲基基团；R4为酸敏感基团、具有7至13个碳原子的脂环烃基团，其具有酸敏感基团、具有7至13个碳原子的脂环烃基团，其具有羧基基团，或具有3至13个碳原子的碳氢基团，其具有环氧基团；R6为氢原子、具有1至12个碳原子的碳氢基团，或具有7至13个碳原子的脂环烃基团，其具有羧基基团；x、y和z是可选值，满足x+y+z=1，0树脂：其中，R8为氢原子或甲基基团，R9为具有脂环内酯结构的7至16个碳原子的碳氢基团。
• POLYMERIZABLE MONOMER, POLYMER COMPOUND, BIOLOGICAL ELECTRODE COMPOSITION, BIOLOGICAL ELECTRODE, AND METHOD FOR PRODUCING BIOLOGICAL ELECTRODE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180197653A1

  公开（公告）日：2018-07-12

  The present invention provides: a biological electrode composition formable a living body contact layer for a biological electrode which is excellent in conductivity and biocompatibility, as well as light in the weight thereof and producible at a low cost, and in addition, which does not cause a significant decrease in the conductivity thereof regardless of under a water-wet condition and a dry condition; a polymer compound which can be suitably used for the biological electrode composition; a polymerizable monomer suitable as a raw material of the polymer compound; a biological electrode having a living body contact layer formed of the biological electrode composition; and a method for producing the same; and wherein, the polymerizable monomer is represented by the following general formula (1).
• BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, AND METHOD FOR MANUFACTURING BIO-ELECTRODE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180168470A1

  公开（公告）日：2018-06-21

  The present invention provides a bio-electrode composition including a polymer compound having both an ionic repeating unit A and a (meth)acrylate repeating unit B, wherein the ionic repeating unit A is a repeating unit selected from the group consisting of sodium salt, potassium salt, and ammonium salt having either or both partial structures shown by the following general formulae (1-1) and (1-2), and the (meth)acrylate repeating unit B is a repeating unit shown by the following general formula (2). This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which can be manufactured at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried.