9-(8-methoxyquinolin-5-yl)carbazole | 872008-63-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9-(8-methoxyquinolin-5-yl)carbazole
• CAS: 872008-63-4
• 化学式: C₂₂H₁₆N₂O
• 分子量: 324.382
• InChiKey: NFXZHRBEOIIKJQ-UHFFFAOYSA-N

物化性质

• 沸点：
  541.8±50.0 °C(Predicted)
• 密度：
  1.22±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.34
• 重原子数：
  25.0
• 可旋转键数：
  2.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  27.05
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  9-(8-methoxyquinolin-5-yl)carbazole 在 氢溴酸 作用下， 以 溶剂黄146 为溶剂， 生成 5-carbazol-9-ylquinolin-8-ol
  参考文献：
  名称：

  A soluble 5-carbazolium-8-hydroxyquinoline Al(III) complex as a dipolar luminescent material

  摘要：

  A novel 8-hydroxyquinoline derivative with a carbazole group substituting in the 5-position of quinoline was synthesized, where carbazole acted as a hole transporter. The single crystal of this 8-hydroxyquinoline derivative was obtained. Its coordination complex with Al(III) was also synthesized. This complex with the ability of hole transportation and electron transportation simultaneously was soluble in common organic solvents and showed yellow luminescence with high quantum yield. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2005.09.190
• 作为产物：
  描述：

  5-溴-8-羟基喹啉 在 18-冠醚-6 copper(l) iodide 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 生成 9-(8-methoxyquinolin-5-yl)carbazole
  参考文献：
  名称：

  A soluble 5-carbazolium-8-hydroxyquinoline Al(III) complex as a dipolar luminescent material

  摘要：

  A novel 8-hydroxyquinoline derivative with a carbazole group substituting in the 5-position of quinoline was synthesized, where carbazole acted as a hole transporter. The single crystal of this 8-hydroxyquinoline derivative was obtained. Its coordination complex with Al(III) was also synthesized. This complex with the ability of hole transportation and electron transportation simultaneously was soluble in common organic solvents and showed yellow luminescence with high quantum yield. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2005.09.190