| 1578258-73-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• CAS: 1578258-73-7
• 化学式: C₃₀H₁₆O₂
• 分子量: 408.456
• InChiKey: SZMSBADRVCPNCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.94
• 重原子数：
  32.0
• 可旋转键数：
  0.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.28
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  dinaphtho-[2,1-b;2′,3′-d]furan-6-ol 、 2,3-二羟基萘 在 甲烷磺酸 作用下， 以 邻二甲苯 为溶剂， 反应 120.0h， 以13%的产率得到
  参考文献：
  名称：

  Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives

  摘要：

  The construction of dinaphtho[2,1-b;2',3'-d]furan-6-ol was developed via a dehydration reaction involving two molecules of 2,3-dihydroxynaphthalene in the presence of a strong acid. Starting from the dinaphthofuran, a variety of butterfly shaped derivatives were synthesized. The optical properties of these compounds were investigated with special attention to the dihedral angle formed by adjacent dinaphthofuran rings and/or the sizes of the fused aromatic rings.

  DOI：

  10.1021/jo500085a

文献信息

• Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives
  作者：Kentaro Nakanishi、Takahiro Sasamori、Kouji Kuramochi、Norihiro Tokitoh、Takeo Kawabata、Kazunori Tsubaki

  DOI：10.1021/jo500085a

  日期：2014.3.21

  The construction of dinaphtho[2,1-b;2',3'-d]furan-6-ol was developed via a dehydration reaction involving two molecules of 2,3-dihydroxynaphthalene in the presence of a strong acid. Starting from the dinaphthofuran, a variety of butterfly shaped derivatives were synthesized. The optical properties of these compounds were investigated with special attention to the dihedral angle formed by adjacent dinaphthofuran rings and/or the sizes of the fused aromatic rings.