5-[(1,1,2,4,4,5,5,6,6,6-decafluoro-3-oxahexoxy)methyl]-bicyclo[2.2.1]hept-2-ene | 908372-20-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-[(1,1,2,4,4,5,5,6,6,6-decafluoro-3-oxahexoxy)methyl]-bicyclo[2.2.1]hept-2-ene
• 英文别名: 5-[(1,1,2,4,4,5,5,6,6,6-Decafluoro-3-oxahexoxy)methyl]-bicyclo[2.2.1]hept-2-ene；5-[[1,1,2-trifluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)ethoxy]methyl]bicyclo[2.2.1]hept-2-ene
• CAS: 908372-20-3
• 化学式: C₁₃H₁₂F₁₀O₂
• 分子量: 390.221
• InChiKey: SSKHDIDCIRDFQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  、 二甲基亚砜 、 5-降冰片烯-2-甲醇 、 氢氧化钾 、 全氟正丙基乙烯基醚 、 在 ice 、 水 作用下， 以 水 为溶剂， 反应 1.33h， 以there is obtained 217.1 g product的产率得到5-[(1,1,2,4,4,5,5,6,6,6-decafluoro-3-oxahexoxy)methyl]-bicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Norbornenylmethyl fluoroalkyl ethers

  摘要：

  描述了一种通过将二环(2,2,1)庚-5-烯-2-甲醇与氟(烷基乙烯醚)反应制备的新单体，即诺博烯基甲基氟烷基醚。这些单体可用于制备聚合物，如用于光阻的疏水性、抗水解性聚合物，特别是用于193nm光的浸没式光刻影像。

  公开号：

  US20070191560A1

文献信息

• GENERATION OF ENDO- AND/OR EXO-NORBORNENECARBOXALDEHYDE AS AN INTERMEDIATE TO FUNCTIONALIZED NORBORNENES
  申请人：Bell Andrew

  公开号：US20090118539A1

  公开（公告）日：2009-05-07

  Embodiments in accordance with the present invention provide for forming essentially pure diastereomers of 5/6-substituted norbornene-type monomers. Further, embodiments in accordance with the present invention encompass polymerizing such diastereomers to form addition or ROMP polymers where a desired exo-/endo-ratio of the diastereomers is provided to the polymerization, such ratio designed to provide a desired ratio of endo-/exo-structured repeating units for a resulting polymer to have desired physical or chemical properties.

  根据本发明的实施例，提供形成基本纯的5/6-取代去氢莰烯型单体的异构体。此外，根据本发明的实施例涵盖聚合这种异构体以形成加成或ROMP聚合物，其中所提供给聚合反应的异构体的期望外/内比例设计为提供所得聚合物具有期望的物理或化学性质的外/内结构重复单元的期望比例。
• Gate insulator layer for electronic devices
  申请人：Merck Patent GmbH

  公开号：EP2676979A1

  公开（公告）日：2013-12-25

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as gate insulator layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin gate insulator and processes for preparing such polycycloolefin gate insulator layers and electronic devices.

  根据本发明的实施方案，可在电子设备中使用聚环烯烃，更具体地说，可将这种聚环烯烃用作制造电子设备的栅极绝缘层、包含这种聚环烯烃栅极绝缘层的电子设备以及制备这种聚环烯烃栅极绝缘层和电子设备的工艺。
• Fluorine free photopatternable phenol functional group containing polymer compositions
  申请人：PROMERUS, LLC

  公开号：US10054854B2

  公开（公告）日：2018-08-21

  Various polycycloolefinic polymers containing phenolic pendent groups and compositions thereof useful for forming self-imageable films encompassing such polymers are disclosed. Such polymers encompass norbornene-type repeating units containing phenolic pendent groups which contain very low levels of fluorine containing monomers. The films formed from such polymer compositions provide self imageable, low-k, thermally stable layers for use in microelectronic and optoelectronic devices.

  本发明公开了各种含酚醛悬垂基团的聚环烯烃聚合物及其用于形成包含此类聚合物的自成像薄膜的组合物。此类聚合物包含降冰片烯类重复单元，其中含有含氟单体含量极低的酚醛悬垂基团。由此类聚合物组合物形成的薄膜具有自成像、低 K 值、热稳定的特性，可用于微电子和光电设备。
• Permanent dielectric compositions containing photoacid generator and base
  申请人：PROMERUS, LLC

  公开号：US10429734B2

  公开（公告）日：2019-10-01

  Embodiments encompassing a series of compositions containing photoacid generator (PAG) and a base are disclosed and claimed. The compositions are useful as permanent dielectric materials. More specifically, embodiments encompassing compositions containing a series of copolymers of a variety of norbornene-type cycloolefinic monomers and maleic anhydride in which maleic anhydride is fully or partially hydrolyzed (i.e., ring opened and fully or partially esterified), PAG and a base, which are useful in forming permanent dielectric materials having utility in a variety of electronic material applications, among various other uses, are disclosed.

  本发明公开了一系列包含光酸发生器（PAG）和基质的组合物，并提出了权利要求。这些组合物可用作永久介电材料。更具体地说，本发明公开了包含多种降冰片烯类环烯烃单体和马来酸酐的一系列共聚物（其中马来酸酐完全或部分水解（即开环和完全或部分酯化））、PAG 和碱的组合物的实施方案，这些组合物可用于形成在各种电子材料应用中有用的永久介电材料。
• Nadic anhydride polymers and photosensitive compositions derived therefrom
  申请人：PROMERUS, LLC

  公开号：US10591818B2

  公开（公告）日：2020-03-17

  Various vinyl addition polymers of nadic anhydride are disclosed. Examples of such polymers include copolymers and terpolymers of nadic anhydride with a wide variety of norbornene-type monomers. The nadic anhydride polymers are found to be useful in forming a wide variety of photosensitive compositions, both positive and negative, which are capable of forming high resolution imagable films exhibiting excellent dielectric properties (low-k) and thermal properties, and thus are useful in the fabrication of a variety of microelectronic and optoelectronic devices, among others.

  本文公开了纳丁酸酐的各种乙烯基加成聚合物。此类聚合物的例子包括纳丁酸酐与各种降冰片烯类单体的共聚物和三元共聚物。我们发现萘酸酐聚合物可用于形成各种光敏组合物，包括正性和负性组合物，这些组合物能够形成高分辨率的可成像薄膜，表现出优异的介电性能（低 K 值）和热性能，因此可用于制造各种微电子和光电设备等。