1,2,4,4-tetramethyl-3-(propen-2-yl)-6-isopropylbicyclo<3.1.0>hexane | 114564-55-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,2,4,4-tetramethyl-3-(propen-2-yl)-6-isopropylbicyclo<3.1.0>hexane
• 英文别名: (1R,2S,3R,5R,6S)-1,2,4,4-tetramethyl-6-propan-2-yl-3-prop-1-en-2-ylbicyclo[3.1.0]hexane
• CAS: 114564-55-5
• 化学式: C₁₆H₂₈
• 分子量: 220.398
• InChiKey: BOGIPZSGZFYWGC-GRYWWWGRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,5-二甲基-2,4-己二烯 在 tris-(4-bromophenyl)aminium hexachloroantimonate 作用下， 以 二氯甲烷 为溶剂， 反应 0.83h， 生成 2,5,7,7,10-pentamethyl-2,4,8-undecatriene 、 1,2,4,4-tetramethyl-3-(propen-2-yl)-6-isopropylbicyclo<3.1.0>hexane
  参考文献：
  名称：

  Mattay, Jochen; Trampe, Gisela; Runsink, Jan, Chemische Berichte, 1988, vol. 121, p. 1693 - 1696

  摘要：

  DOI：

文献信息

• Reactivity of Radical Cations:  Generation, Characterization, and Reactivity of 1,3-Diene Radical Cations¹
  作者：C. S. Q. Lew、J. R. Brisson、L. J. Johnston

  DOI：10.1021/jo9623189

  日期：1997.6.13

  Conjugated diene radical cations have been generated by either photoionization of the parent diene or photosensitized electron transfer using triplet chloranil or 1,4-dicyanonaphthalene/biphenyl in acetonitrile and have been characterized by laser flash photolysis. The radical cations have a moderately strong absorption in the 340-400 nm region with a broader and weaker band at longer wavelength, in agreement with literature data for the same species in matrices. The radical cations react with anionic nucleophiles with rates that approach the diffusion-controlled limit and are insensitive to oxygen. Reaction of the diene radical cation with its precursor diene is the predominant decay pathway in the absence of added nucleophiles or alkenes and occurs with rate constants on the order of 10(8)-10(9) M-1 s(-1). Product studies for 2,5-dimethyl-2,4-hexadiene indicate that this reaction does lead to dimer formation although the major dimeric product results from substantial rearrangement of the initial adduct. The complex chemistry is consistent with the observation of negative curvature at high diene concentrations in the quenching plots for reaction of the diene radical cations with their precursors. Rate constants for reaction of the diene radical cations with methanol range from 1.2 x 10(5) M-1 s(-1) for 2,5-dimethyl-2,4-hexadiene to 1.8 x 10(8) M-1 s(-1) for 2,4-hexadiene and demonstrate the effects of alkyl substitution on the radical cation reactivity. The reactivity of the diene radical cations toward a number of alkyl- and alkoxy-substituted ethylenes was also measured and provides some of the first kinetic data for cross-cycloaddition reactions for simple nonaryl-substituted radical cations.
• Mattay, Jochen; Trampe, Gisela; Runsink, Jan, Chemische Berichte, 1988, vol. 121, p. 1693 - 1696
  作者：Mattay, Jochen、Trampe, Gisela、Runsink, Jan、Meltzow, Wilhelm、Jans, Arnold W. H.

  DOI：——

  日期：——