(tetrabenzoporphirinato)chloromanganese(III) | 161336-80-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (tetrabenzoporphirinato)chloromanganese(III)
• 英文别名: (tetrabenzoporphyrinato)chloromanganese(III)
• CAS: 161336-80-7
• 化学式: C₃₆H₂₀ClMnN₄
• 分子量: 598.973
• InChiKey: HITUJONPTFVIML-YAJYDHHFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (tetrabenzoporphirinato)chloromanganese(III) 在 alkali 作用下， 以 dimethylsulfoxide 为溶剂， 生成 tetrabenzoporphirinatomanganese(II)
  参考文献：
  名称：

  Synthesis and spectral characteristics of (tetrabenzoporphyrinato)chloromanganese(III)

  摘要：

  A method is developed of synthesis of (tetrabenzoporphyrinato)chloromanganese(III) from tetrabenzoporphyrinatocadmium( II) (as a donor of the macrocyclic ligand) and the salts, manganese acetate MnAc2 and dichloromanganese MnCl2, in boiling dimethylformamide in the presence of atmosperic oxygen in 80% yield. It is found that under the conditions of the synthesis tetrabenzoporphyrinatomanganese(II) is formed which can be oxidized by the atmospheric oxygen to (tetrabenzoporphyrinato)chloromanganese(III). Absorption spectra in the visible and infrared regions, R (f) and the data of elemental analysis characterizing the resulting compound are given.

  DOI：

  10.1134/s107036321002026x
• 作为产物：
  描述：

  cadmium(II) 29H,31H-tetrabenzo[b,g,l,q]porphine 在 manganese(ll) chloride 、 盐酸 作用下， 以 N,N-二甲基甲酰胺 、 水 为溶剂， 反应 1.01h， 以80%的产率得到(tetrabenzoporphirinato)chloromanganese(III)
  参考文献：
  名称：

  Synthesis and spectral characteristics of (tetrabenzoporphyrinato)chloromanganese(III)

  摘要：

  A method is developed of synthesis of (tetrabenzoporphyrinato)chloromanganese(III) from tetrabenzoporphyrinatocadmium( II) (as a donor of the macrocyclic ligand) and the salts, manganese acetate MnAc2 and dichloromanganese MnCl2, in boiling dimethylformamide in the presence of atmosperic oxygen in 80% yield. It is found that under the conditions of the synthesis tetrabenzoporphyrinatomanganese(II) is formed which can be oxidized by the atmospheric oxygen to (tetrabenzoporphyrinato)chloromanganese(III). Absorption spectra in the visible and infrared regions, R (f) and the data of elemental analysis characterizing the resulting compound are given.

  DOI：

  10.1134/s107036321002026x