tetrabenzoporphirinatomanganese(II) | 408497-84-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrabenzoporphirinatomanganese(II)
• 英文别名: manganese phthalocyanine
• CAS: 408497-84-7
• 化学式: C₃₆H₂₀MnN₄
• 分子量: 563.52
• InChiKey: YPLQHBQTCVIMRS-XTPDIVBZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tetrabenzoporphirinatomanganese(II) 、 四苯基氯化膦 以 N,N-二甲基甲酰胺 为溶剂， 生成 Mn^III(tetrabenzoporphyrinato^•−)Cl₂
  参考文献：
  名称：

  包含四苯并卟啉中性自由基的单组分分子晶体中的金刚石晶格

  摘要：

  Co III (tbp˙ − )(CN) 2的单组分分子自由基晶体（其中 tbp = 四苯并卟啉配体）具有金刚石晶格，被制造为三维狄拉克电子系统的潜在候选者。能带结构计算表明费米能级位于狄拉克点。在 2.4 GPa 的施加下，在 2 K 下观察到 160 Ω cm 的小电阻率。此外，用 Fe III或 Mn III取代 Co III导致在金刚石晶格系统中引入局部磁矩。 M III (tbp˙ − )L 2晶体将为狄拉克电子系统的研究开辟未知领域。

  DOI：

  10.1039/d3cc05948k
• 作为产物：
  描述：

  (tetrabenzoporphirinato)chloromanganese(III) 在 alkali 作用下， 以 dimethylsulfoxide 为溶剂， 生成 tetrabenzoporphirinatomanganese(II)
  参考文献：
  名称：

  Synthesis and spectral characteristics of (tetrabenzoporphyrinato)chloromanganese(III)

  摘要：

  A method is developed of synthesis of (tetrabenzoporphyrinato)chloromanganese(III) from tetrabenzoporphyrinatocadmium( II) (as a donor of the macrocyclic ligand) and the salts, manganese acetate MnAc2 and dichloromanganese MnCl2, in boiling dimethylformamide in the presence of atmosperic oxygen in 80% yield. It is found that under the conditions of the synthesis tetrabenzoporphyrinatomanganese(II) is formed which can be oxidized by the atmospheric oxygen to (tetrabenzoporphyrinato)chloromanganese(III). Absorption spectra in the visible and infrared regions, R (f) and the data of elemental analysis characterizing the resulting compound are given.

  DOI：

  10.1134/s107036321002026x

文献信息

• A novel and green route for solvothermal synthesis of manganese phthalocyanine crystals
  作者：Dapeng Li、Suxiang Ge、Guofu Sun、Qin He、Baojun Huang、Guizhong Tian、Weiyu Lu、Guobao Li、Yunlong Chen、Shengnan An、Zhi Zheng

  DOI：10.1016/j.dyepig.2014.08.012

  日期：2015.2

  A novel, facile, and green route was proposed for solvothermal synthesis of manganese phthalocyanine (MnPc) crystals. The quadrangular prism-like MnPc crystals could be obtained at 190 degrees C during 3 h with manganese acetate and phthalodinitrile as reactants. The common ethanol was used as solvent and no other chemical additives were required in this reaction system. It is noted that purification of as prepared MnPc crystals was very simple and just required the removal of unreacted reagents washing by hot ethanol and water. Compared to the reported method, this simple synthesis route shows many advantages, such as low cost, facile preparation and purification, especially the nontoxic ethanol used as reaction medium. (C) 2014 Elsevier Ltd. All rights reserved.