[bppp2Ir(acac)] | 1309356-82-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: [bppp2Ir(acac)]
• 英文别名: [(2,5-bis(4',4''-N,N-diphenylamino)phenyl pyridine)2Ir(acetylacetonato)]
• CAS: 1309356-82-8
• 化学式: C₈₇H₆₇IrN₆O₂
• 分子量: 1420.75
• InChiKey: FHNGGUNQPYFEMI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [bppp2Ir(μ-Cl)]2 、 乙酰丙酮 在 Na₂CO₃ 作用下， 以 乙二醇乙醚 为溶剂， 以63%的产率得到[bppp2Ir(acac)]
  参考文献：
  名称：

  Carbazole and arylamine functionalized iridium complexes for efficient electro-phosphorescent light-emitting diodes

  摘要：

  We report the synthesis and characterization of four cyclometalated iridium complexes based on carbazole and arylamine modified 2-phenylpyridine. The carbazole and arylamine groups are linked to 2-phenyl pyridine backbone to enhance the energy harvesting and transfer from host to guest materials. The electrochemical and photophysical properties of the complexes are studied and electroluminescent devices are fabricated. The results show that the complexes with ligands containing carbazole moieties have desirable phosphorescent properties. The device with complex 3 doped PVK (poly (vinylcarbazole)) as emission layer achieves maximum luminous efficiency of 6.56 cd A (1) and maximum brightness of 14448 cd m (2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.095