N,N'-bis[(1S,5R)-6,6-dimethyl-bicyclo[3.3.1]hept-2-en-2-ylmethyl]-ethane-1,2-diamine | 1010824-85-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: N,N'-bis[(1S,5R)-6,6-dimethyl-bicyclo[3.3.1]hept-2-en-2-ylmethyl]-ethane-1,2-diamine
• 英文别名: N,N'-bis[[(1S,5R)-6,6-dimethylbicyclo[3.3.1]hept-2-en-2-yl]methyl]-1,2-ethylenediamine；N,N'-bis{[(1s,5r)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl}-1,2-ethylenediamine；N,N'-bis[[(1S,5R)-6,6-dimethyl-2-bicyclo[3.1.1]hept-2-enyl]methyl]ethane-1,2-diamine
• CAS: 1010824-85-7
• 化学式: C₂₂H₃₆N₂
• 分子量: 328.541
• InChiKey: HNJKBWFGBVTKFC-UAFMIMERSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-bis[(1S,5R)-6,6-dimethyl-bicyclo[3.3.1]hept-2-en-2-ylmethyl]-ethane-1,2-diamine 、 bis(acetonitrile)palladium(II) bromide 在 sodium acetate 作用下， 以 乙腈 为溶剂， 以77%的产率得到[PdBr2(N,N'-bis[[(1S,5R)-6,6-dimethylbicyclo[3.3.1]hept-2-en-2-yl]methyl]-1,2-ethylenediamine)]
  参考文献：
  名称：

  Palladium complexes based on optically active terpene derivatives of ethylenediamine

  摘要：

  Novel chiral palladium diamino complexes with the asymmetric donor N atom Pd(En*)X-2 (where En* = N,N'-bis{[(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl}-1,2-ethylenediamine; X = Cl and Br) were obtained and characterized. Nitrogen-containing derivatives of the natural monoterpene a-pinene were studied as accessible optically active ligands.

  DOI：

  10.1134/s1070328408110110
• 作为产物：
  描述：

  (+)-(1S)-6,6-二甲基-双环[3.1.1]庚-2-烯-2-甲醛 、 乙二胺 在 sodium sulfate 、 sodium tetrahydroborate 作用下， 以 苯 、 乙醇 为溶剂， 反应 9.5h， 以69%的产率得到N,N'-bis[(1S,5R)-6,6-dimethyl-bicyclo[3.3.1]hept-2-en-2-ylmethyl]-ethane-1,2-diamine
  参考文献：
  名称：

  Synthesis of new enantiomeric 1,2-diamines containing a myrtenyl fragment

  摘要：

  Some new bi- and tridentate nitrogen-containing, chiral ligands were synthesized on the basis of natural monoterpenoids, (+)- and (-)-myrtenals and (+)-myrtenol. A procedure was proposed for the synthesis of unsymmetrical ligands containing terpenoid and o-hydroxyphenyl fragments.

  DOI：

  10.1134/s1070428007030037